TY - JOUR
T1 - Dynamical fluctuation effects in glassy colloidal suspensions
AU - Schweizer, Kenneth S.
N1 - Funding Information:
I acknowledge support for my work in the area of glassy colloidal systems from the National Science Foundation via DMR-0117792 and the U.S. Department of Energy, Division of Materials Sciences via DEFG02-91ER45439. I am grateful to G. Yatsenko, K. Chen and A. Jayaraman and for their invaluable assistance in preparing the figures.
PY - 2007/12
Y1 - 2007/12
N2 - Fundamental understanding of heterogeneous dynamics in concentrated glassy hard sphere fluids and colloidal suspensions, even at the single particle level, requires major theoretical advances. Recent simulations and confocal microscopy experiments suggest strong nongaussian dynamical fluctuation effects and activated transport emerge well before an apparent kinetic glass transition is reached. New theoretical approaches that can predict the observable signatures of intermittent large amplitude motions and the associated fluctuation phenomena are discussed. Comparisons are made with experiments, computer simulations, and prior theory for average dynamical properties.
AB - Fundamental understanding of heterogeneous dynamics in concentrated glassy hard sphere fluids and colloidal suspensions, even at the single particle level, requires major theoretical advances. Recent simulations and confocal microscopy experiments suggest strong nongaussian dynamical fluctuation effects and activated transport emerge well before an apparent kinetic glass transition is reached. New theoretical approaches that can predict the observable signatures of intermittent large amplitude motions and the associated fluctuation phenomena are discussed. Comparisons are made with experiments, computer simulations, and prior theory for average dynamical properties.
KW - Activated barrier hopping
KW - Caging
KW - Colloidal suspensions
KW - Dynamic heterogeneity
KW - Glassy dynamics
KW - Hard spheres
KW - Nongaussian fluctuations
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U2 - 10.1016/j.cocis.2007.07.013
DO - 10.1016/j.cocis.2007.07.013
M3 - Review article
AN - SCOPUS:35448963055
SN - 1359-0294
VL - 12
SP - 297
EP - 306
JO - Current Opinion in Colloid and Interface Science
JF - Current Opinion in Colloid and Interface Science
IS - 6
ER -