Directed synthesis of mixed metal chalcogenide clusters: oxidative additions of Fe2 μ2-E2)(CO)6 (E = S, Se, Te)

David A. Lesch, Thomas B. Rauchfuss

Research output: Contribution to journalArticlepeer-review

Abstract

The reaction of Fe22-E2)(CO)6 with M(PPh3)2 (C2H4) affords quantitative yields of (CO)6Fe23-E)2 M(PPh3)2 (E = S, Se, Te; M = Pt, Pd), which were characterized by analytical data, molecular weight measurements, IR, and heteronuclear NMR.

Original languageEnglish (US)
Pages (from-to)C6-C8
JournalJournal of Organometallic Chemistry
Volume199
Issue number1
DOIs
StatePublished - Jan 1 1980

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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