Direct observations of the sintering of silver nanoparticles on single crystal copper by in-situ UHV TEM

M. Yeadon, J. C. Yang, R. S. Averback, J. W. Bullard, J. M. Gibson

Research output: Contribution to journalConference articlepeer-review

Abstract

Using a novel ultrahigh vacuum (UHV) transmission electron microscope with in-situ UHV sputtering attachment we have studied the sintering of copper and silver nanoparticles with single crystal copper substrates. Copper and silver particles deposited on (001) copper initially assume random orientations. Upon annealing, however, the particles reorient and assume an epitaxial orientation with the substrate. In the case of copper on copper, homoepitaxy occurs by a process involving sintering and grain growth. In the case of silver on copper, we have observed the particles to wet the substrate surface and sinter to form a thin epitaxial film with the orientation relationship (111)Ag∥(001)Cu, [110]Ag∥[110]Cu.

Original languageEnglish (US)
Pages (from-to)283-288
Number of pages6
JournalMaterials Research Society Symposium - Proceedings
Volume501
StatePublished - 1998
EventProceedings of the 1997 MRS Fall Symposium - Boston, MA, USA
Duration: Dec 2 1997Dec 4 1997

ASJC Scopus subject areas

  • General Materials Science
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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