Direct observation of distributions of mixed clusters of coadsorbed species in zeolite NaA

A. K. Jameson; C. J. Jameson; A. C. de Dios; E. Oldfield; R. E. Gerald

doi:10.1016/S0167-2991(06)81098-0

Direct observation of distributions of mixed clusters of coadsorbed species in zeolite NaA

A. K. Jameson, C. J. Jameson, A. C. de Dios, E. Oldfield, R. E. Gerald

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

We show for the first time that the individual peaks corresponding to Xe_n clusters inside the alpha cages of zeolite NaA can be narrowed under magic angle spinning. Under these high resolution conditions we observe the individual peaks corresponding to mixed dusters Xe_nKr_m inside the alpha cages, which allows the direct determination of the distribution of coadsorbates in a microporous solid for the first time.

Original language	English (US)
Pages (from-to)	85-86
Number of pages	2
Journal	Studies in Surface Science and Catalysis
Volume	98
Issue number	C
DOIs	https://doi.org/10.1016/S0167-2991(06)81098-0
State	Published - Jan 1 1995

ASJC Scopus subject areas

Catalysis
Condensed Matter Physics
Physical and Theoretical Chemistry
Surfaces, Coatings and Films
Materials Chemistry

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10.1016/S0167-2991(06)81098-0

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abstract = "We show for the first time that the individual peaks corresponding to Xen clusters inside the alpha cages of zeolite NaA can be narrowed under magic angle spinning. Under these high resolution conditions we observe the individual peaks corresponding to mixed dusters XenKrm inside the alpha cages, which allows the direct determination of the distribution of coadsorbates in a microporous solid for the first time.",

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AU - Jameson, A. K.

AU - Jameson, C. J.

AU - de Dios, A. C.

AU - Oldfield, E.

AU - Gerald, R. E.

PY - 1995/1/1

Y1 - 1995/1/1

N2 - We show for the first time that the individual peaks corresponding to Xen clusters inside the alpha cages of zeolite NaA can be narrowed under magic angle spinning. Under these high resolution conditions we observe the individual peaks corresponding to mixed dusters XenKrm inside the alpha cages, which allows the direct determination of the distribution of coadsorbates in a microporous solid for the first time.

AB - We show for the first time that the individual peaks corresponding to Xen clusters inside the alpha cages of zeolite NaA can be narrowed under magic angle spinning. Under these high resolution conditions we observe the individual peaks corresponding to mixed dusters XenKrm inside the alpha cages, which allows the direct determination of the distribution of coadsorbates in a microporous solid for the first time.

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JO - Studies in Surface Science and Catalysis

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IS - C

ER -

Direct observation of distributions of mixed clusters of coadsorbed species in zeolite NaA

Abstract

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