Diphenyl-phosphine sulfide

Priyanka P. Pitroda; Ansonia H. Badgett; Geralyn A. Dickey; Danielle L. Gray; Quinetta D. Shelby

doi:10.1107/S1600536809034059

Diphenyl-phosphine sulfide

Priyanka P. Pitroda, Ansonia H. Badgett, Geralyn A. Dickey, Danielle L. Gray, Quinetta D. Shelby

School of Chemical Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

In the title compound, C27H₈6P2S, the P- C- P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)].

Original language	English (US)
Pages (from-to)	o2307
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	65
Issue number	10
DOIs	https://doi.org/10.1107/S1600536809034059
State	Published - 2009

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

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10.1107/S1600536809034059

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title = "Diphenyl-phosphine sulfide",

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AU - Pitroda, Priyanka P.

AU - Badgett, Ansonia H.

AU - Dickey, Geralyn A.

AU - Gray, Danielle L.

AU - Shelby, Quinetta D.

PY - 2009

Y1 - 2009

N2 - In the title compound, C27H86P2S, the P- C- P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)].

AB - In the title compound, C27H86P2S, the P- C- P angle is 114.33 (13)°. The bond distances are longer and the bond angles are smaller at the P atom bonded to the o-tolyl groups owing to the presence of a lone pair of electrons. One phenyl ring is disordered over three sites [occupancies 0.317 (8), 0.250 (8), and 0.433 (6)] and the other phenyl ring is disordered over two sites [occupancies 0.871 (6) and 0.129 (6)].

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Diphenyl-phosphine sulfide

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