Dinuclear palladium(III) complexes with a single unsupported bridging halide ligand: Reversible formation from mononuclear palladium(II) or palladium(IV) precursors

Julia R. Khusnutdinova; Nigam P. Rath; Liviu M. Mirica

doi:10.1002/anie.201100928

Dinuclear palladium(III) complexes with a single unsupported bridging halide ligand: Reversible formation from mononuclear palladium(II) or palladium(IV) precursors

Julia R. Khusnutdinova, Nigam P. Rath, Liviu M. Mirica

Research output: Contribution to journal › Article › peer-review

Abstract

Stable Pd^III: Dinuclear Pd^III complexes of the tridentate ligand trimethyltriazacyclononane (Me₃tacn) were obtained by one-electron oxidation of mononuclear Pd^II precursors. Further oxidation led reversibly to mononuclear Pd^IV species. The Pd ^II and Pd^III complexes are shown to be involved in the catalytic Kharasch addition of polyhaloalkanes to alkenes.

Original language	English (US)
Pages (from-to)	5532-5536
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	24
DOIs	https://doi.org/10.1002/anie.201100928
State	Published - Jun 6 2011
Externally published	Yes

Keywords

Kharasch reaction
N ligands
chain compounds
dinuclear complexes
palladium

ASJC Scopus subject areas

Catalysis
General Chemistry

Online availability

10.1002/anie.201100928

Library availability

Discover UIUC Full Text

Cite this

Dinuclear palladium(III) complexes with a single unsupported bridging halide ligand: Reversible formation from mononuclear palladium(II) or palladium(IV) precursors. / Khusnutdinova, Julia R.; Rath, Nigam P.; Mirica, Liviu M.
In: Angewandte Chemie - International Edition, Vol. 50, No. 24, 06.06.2011, p. 5532-5536.

Research output: Contribution to journal › Article › peer-review

@article{2300df845fb742bfb1518613d0cb897e,

title = "Dinuclear palladium(III) complexes with a single unsupported bridging halide ligand: Reversible formation from mononuclear palladium(II) or palladium(IV) precursors",

abstract = "Stable PdIII: Dinuclear PdIII complexes of the tridentate ligand trimethyltriazacyclononane (Me3tacn) were obtained by one-electron oxidation of mononuclear PdII precursors. Further oxidation led reversibly to mononuclear PdIV species. The Pd II and PdIII complexes are shown to be involved in the catalytic Kharasch addition of polyhaloalkanes to alkenes.",

keywords = "Kharasch reaction, N ligands, chain compounds, dinuclear complexes, palladium",

author = "Khusnutdinova, {Julia R.} and Rath, {Nigam P.} and Mirica, {Liviu M.}",

year = "2011",

month = jun,

day = "6",

doi = "10.1002/anie.201100928",

language = "English (US)",

volume = "50",

pages = "5532--5536",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley & Sons, Ltd.",

number = "24",

}

TY - JOUR

T1 - Dinuclear palladium(III) complexes with a single unsupported bridging halide ligand

T2 - Reversible formation from mononuclear palladium(II) or palladium(IV) precursors

AU - Khusnutdinova, Julia R.

AU - Rath, Nigam P.

AU - Mirica, Liviu M.

PY - 2011/6/6

Y1 - 2011/6/6

N2 - Stable PdIII: Dinuclear PdIII complexes of the tridentate ligand trimethyltriazacyclononane (Me3tacn) were obtained by one-electron oxidation of mononuclear PdII precursors. Further oxidation led reversibly to mononuclear PdIV species. The Pd II and PdIII complexes are shown to be involved in the catalytic Kharasch addition of polyhaloalkanes to alkenes.

AB - Stable PdIII: Dinuclear PdIII complexes of the tridentate ligand trimethyltriazacyclononane (Me3tacn) were obtained by one-electron oxidation of mononuclear PdII precursors. Further oxidation led reversibly to mononuclear PdIV species. The Pd II and PdIII complexes are shown to be involved in the catalytic Kharasch addition of polyhaloalkanes to alkenes.

KW - Kharasch reaction

KW - N ligands

KW - chain compounds

KW - dinuclear complexes

KW - palladium

UR - http://www.scopus.com/inward/record.url?scp=79958067232&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=79958067232&partnerID=8YFLogxK

U2 - 10.1002/anie.201100928

DO - 10.1002/anie.201100928

M3 - Article

C2 - 21557420

AN - SCOPUS:79958067232

SN - 1433-7851

VL - 50

SP - 5532

EP - 5536

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 24

ER -

Dinuclear palladium(III) complexes with a single unsupported bridging halide ligand: Reversible formation from mononuclear palladium(II) or palladium(IV) precursors

Abstract

Keywords

ASJC Scopus subject areas

Online availability

Library availability

Related links

Fingerprint

Cite this