Abstract
The dimetal hexaalkoxides M2(OR)6 of molybdenum and especially tungsten display a rich chemistry. The dimolybdenum analogs are less prone to undergo a reaction with alkynes. The general procedures include experiments carried out in a dry nitrogen atmosphere in a glove box except where noted. This chapter discusses the procedures and properties of hexa(tert-butoxy)dimolybdenum(III), hexakis(2-trifluoromethyl-2-propoxy) dimolybdenum(III), sodium heptachloropentakis, hexa(tert-butoxy)ditungsten(III), and hexakis(2-trifluoromethyl-2-propoxy)ditungsten(III).
| Original language | English (US) |
|---|---|
| Title of host publication | Inorganic Syntheses |
| Publisher | Wiley-Blackwell |
| Pages | 96-102 |
| Number of pages | 7 |
| Volume | 36 |
| ISBN (Electronic) | 9781118744994 |
| ISBN (Print) | 9781118744871 |
| DOIs | |
| State | Published - May 12 2014 |
Keywords
- Dimolybdenum analogs
- Ditungsten hexa alkoxides
- Hexa(tert-butoxy)ditungsten(III)
- Sodium heptachloropentakis
ASJC Scopus subject areas
- Chemistry(all)
- Engineering(all)
- Materials Science(all)