Dielectric response of a dilute suspension of spheres with thin double layers in an asymmetric electrolyte

E. John Hinch; John D. Sherwood; Weng C. Chew; Pabitra N. Sen

doi:10.1039/F29848000535

Dielectric response of a dilute suspension of spheres with thin double layers in an asymmetric electrolyte

E. John Hinch, John D. Sherwood, Weng C. Chew, Pabitra N. Sen

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Abstract

The low-frequency dielectric response of a suspension of spherical particles surrounded by thin double layers has been studied and the analysis of Dukhin and Shilov has been extended to asymmetric electrolytes. In addition to the cases of constant surface charge density and of constant surface potential, the case in which changes in the surface charge density are determined by changes in the surface potential according to a first-order kinetic equation has also been examined.

Original language	English (US)
Pages (from-to)	535-551
Number of pages	17
Journal	Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
Volume	80
Issue number	5
DOIs	https://doi.org/10.1039/F29848000535
State	Published - 1984
Externally published	Yes

ASJC Scopus subject areas

Atomic and Molecular Physics, and Optics
Physical and Theoretical Chemistry

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10.1039/F29848000535

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abstract = "The low-frequency dielectric response of a suspension of spherical particles surrounded by thin double layers has been studied and the analysis of Dukhin and Shilov has been extended to asymmetric electrolytes. In addition to the cases of constant surface charge density and of constant surface potential, the case in which changes in the surface charge density are determined by changes in the surface potential according to a first-order kinetic equation has also been examined.",

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AU - Hinch, E. John

AU - Sherwood, John D.

AU - Chew, Weng C.

AU - Sen, Pabitra N.

PY - 1984

Y1 - 1984

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AB - The low-frequency dielectric response of a suspension of spherical particles surrounded by thin double layers has been studied and the analysis of Dukhin and Shilov has been extended to asymmetric electrolytes. In addition to the cases of constant surface charge density and of constant surface potential, the case in which changes in the surface charge density are determined by changes in the surface potential according to a first-order kinetic equation has also been examined.

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ER -

Dielectric response of a dilute suspension of spheres with thin double layers in an asymmetric electrolyte

Abstract

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