Dielectric response of a dilute suspension of spheres with thin double layers in an asymmetric electrolyte

E. John Hinch, John D. Sherwood, Weng C. Chew, Pabitra N. Sen

Research output: Contribution to journalArticlepeer-review

Abstract

The low-frequency dielectric response of a suspension of spherical particles surrounded by thin double layers has been studied and the analysis of Dukhin and Shilov has been extended to asymmetric electrolytes. In addition to the cases of constant surface charge density and of constant surface potential, the case in which changes in the surface charge density are determined by changes in the surface potential according to a first-order kinetic equation has also been examined.

Original languageEnglish (US)
Pages (from-to)535-551
Number of pages17
JournalJournal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics
Volume80
Issue number5
DOIs
StatePublished - Dec 1 1984

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Physical and Theoretical Chemistry

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