The low-frequency dielectric response of a suspension of spherical particles surrounded by thin double layers has been studied and the analysis of Dukhin and Shilov has been extended to asymmetric electrolytes. In addition to the cases of constant surface charge density and of constant surface potential, the case in which changes in the surface charge density are determined by changes in the surface potential according to a first-order kinetic equation has also been examined.
|Original language||English (US)|
|Number of pages||17|
|Journal||Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics|
|State||Published - 1984|
ASJC Scopus subject areas
- Atomic and Molecular Physics, and Optics
- Physical and Theoretical Chemistry