Development and mechanism of an enantioselective bromocycloetherification reaction via Lewis base/chiral Brønsted acid cooperative catalysis

Scott E. Denmark; Matthew T. Burk

doi:10.1002/chir.22259

Development and mechanism of an enantioselective bromocycloetherification reaction via Lewis base/chiral Brønsted acid cooperative catalysis

Scott E. Denmark, Matthew T. Burk

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The development of a binary catalyst system for bromocycloetherification, consisting of an achiral Lewis base and a chiral Brønsted acid, is described in detail. The results of preliminary kinetic studies are also presented. Chirality 26:343-354, 2013.

Original language	English (US)
Pages (from-to)	344-355
Number of pages	12
Journal	Chirality
Volume	26
Issue number	7
DOIs	https://doi.org/10.1002/chir.22259
State	Published - Jul 2014

Keywords

Lewis base
cooperative catalysis
enantioselective
halofunctionalization

ASJC Scopus subject areas

Analytical Chemistry
Catalysis
Pharmacology
Drug Discovery
Spectroscopy
Organic Chemistry

Online availability

10.1002/chir.22259

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abstract = "The development of a binary catalyst system for bromocycloetherification, consisting of an achiral Lewis base and a chiral Br{\o}nsted acid, is described in detail. The results of preliminary kinetic studies are also presented. Chirality 26:343-354, 2013.",

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KW - enantioselective

KW - halofunctionalization

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Development and mechanism of an enantioselective bromocycloetherification reaction via Lewis base/chiral Brønsted acid cooperative catalysis

Abstract

Keywords

ASJC Scopus subject areas

Online availability

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