Designed synthesis of families of misfit-layered compounds

Qiyin Lin; Colby L. Heideman; Ngoc Nguyen; Paul Zschack; Catalin Chiritescu; David G Cahill; David C. Johnson

doi:10.1002/ejic.200800158

Designed synthesis of families of misfit-layered compounds

Qiyin Lin, Colby L. Heideman, Ngoc Nguyen, Paul Zschack, Catalin Chiritescu, David G Cahill, David C. Johnson

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis of several new families of misfit-layered compounds is demonstrated. These compounds are crystalline along the c-axis and in the ab-plane, but show very short coherence lengths between ab-planes. This disorder leads to ultra-low and tunable thermal conductivity. Annealing isostructural samples under a chalcogen vapour until equilibrium is reached results in reproducible Seebeck and resistivity values.

Original language	English (US)
Pages (from-to)	2382-2385
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	15
DOIs	https://doi.org/10.1002/ejic.200800158
State	Published - May 2008

Keywords

Crystal engineering
Incommensurate structure
Layered compounds
Nanostructure
Synthesis design

ASJC Scopus subject areas

Inorganic Chemistry

Online availability

10.1002/ejic.200800158

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keywords = "Crystal engineering, Incommensurate structure, Layered compounds, Nanostructure, Synthesis design",

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journal = "European Journal of Inorganic Chemistry",

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AU - Lin, Qiyin

AU - Heideman, Colby L.

AU - Nguyen, Ngoc

AU - Zschack, Paul

AU - Chiritescu, Catalin

AU - Cahill, David G

AU - Johnson, David C.

PY - 2008/5

Y1 - 2008/5

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AB - The synthesis of several new families of misfit-layered compounds is demonstrated. These compounds are crystalline along the c-axis and in the ab-plane, but show very short coherence lengths between ab-planes. This disorder leads to ultra-low and tunable thermal conductivity. Annealing isostructural samples under a chalcogen vapour until equilibrium is reached results in reproducible Seebeck and resistivity values.

KW - Crystal engineering

KW - Incommensurate structure

KW - Layered compounds

KW - Nanostructure

KW - Synthesis design

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JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 15

ER -

Designed synthesis of families of misfit-layered compounds

Abstract

Keywords

ASJC Scopus subject areas

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