Abstract
This Account chronicles the conceptual development, proof of principle, exploration of scope, and mechanistic investigations of a newly developed class of palladium-catalyzed cross-coupling reactions of silicon derivatives. Under the influence of fluoride activation a myriad of oxygen-containing silicon moieties undergo mild and stereospecific cross-coupling. The diversity of methods for introduction of silicon groupings into organic molecules and the range of organic electrophiles that can be used are outlined.
Original language | English (US) |
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Pages (from-to) | 835-846 |
Number of pages | 12 |
Journal | Accounts of chemical research |
Volume | 35 |
Issue number | 10 |
DOIs | |
State | Published - Oct 2002 |
ASJC Scopus subject areas
- General Chemistry