Derivatized, high surface area, supported nickel catalysts

Ralph G. Nuzzo; Lawrence H. Dubois; Norman E. Bowles; Malaine A. Trecoske

doi:10.1016/0021-9517(84)90131-3

Derivatized, high surface area, supported nickel catalysts

Ralph G. Nuzzo
, Lawrence H. Dubois
, Norman E. Bowles
, Malaine A. Trecoske

Research output: Contribution to journal › Article › peer-review

Abstract

A new and general procedure for preparing high surface area, supported intermetallic compound and alloy catalysts is described. In this technique, the volatile Group IIIA and IVA organometallic compounds SiH₄, Me₆Si₂, Me₆Ge₂, BH₃ · Et₃N, and Et₃Al are decomposed thermally on high surface area nickel, supported on either SiO₂ or Al₂O₃, to yield, directly, mixed metal catalysts of varied composition and structure. Using the competitive dehydrogenation and hydrogenolysis of cyclohexane as model reactions, the effects of intermetallic compound formation on catalytic activity are described.

Original language	English (US)
Pages (from-to)	267-271
Number of pages	5
Journal	Journal of Catalysis
Volume	85
Issue number	1
DOIs	https://doi.org/10.1016/0021-9517(84)90131-3
State	Published - Jan 1984
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

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10.1016/0021-9517(84)90131-3

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abstract = "A new and general procedure for preparing high surface area, supported intermetallic compound and alloy catalysts is described. In this technique, the volatile Group IIIA and IVA organometallic compounds SiH4, Me6Si2, Me6Ge2, BH3 · Et3N, and Et3Al are decomposed thermally on high surface area nickel, supported on either SiO2 or Al2O3, to yield, directly, mixed metal catalysts of varied composition and structure. Using the competitive dehydrogenation and hydrogenolysis of cyclohexane as model reactions, the effects of intermetallic compound formation on catalytic activity are described.",

author = "Nuzzo, \{Ralph G.\} and Dubois, \{Lawrence H.\} and Bowles, \{Norman E.\} and Trecoske, \{Malaine A.\}",

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language = "English (US)",

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AU - Nuzzo, Ralph G.

AU - Dubois, Lawrence H.

AU - Bowles, Norman E.

AU - Trecoske, Malaine A.

PY - 1984/1

Y1 - 1984/1

N2 - A new and general procedure for preparing high surface area, supported intermetallic compound and alloy catalysts is described. In this technique, the volatile Group IIIA and IVA organometallic compounds SiH4, Me6Si2, Me6Ge2, BH3 · Et3N, and Et3Al are decomposed thermally on high surface area nickel, supported on either SiO2 or Al2O3, to yield, directly, mixed metal catalysts of varied composition and structure. Using the competitive dehydrogenation and hydrogenolysis of cyclohexane as model reactions, the effects of intermetallic compound formation on catalytic activity are described.

AB - A new and general procedure for preparing high surface area, supported intermetallic compound and alloy catalysts is described. In this technique, the volatile Group IIIA and IVA organometallic compounds SiH4, Me6Si2, Me6Ge2, BH3 · Et3N, and Et3Al are decomposed thermally on high surface area nickel, supported on either SiO2 or Al2O3, to yield, directly, mixed metal catalysts of varied composition and structure. Using the competitive dehydrogenation and hydrogenolysis of cyclohexane as model reactions, the effects of intermetallic compound formation on catalytic activity are described.

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JO - Journal of Catalysis

JF - Journal of Catalysis

IS - 1

ER -

Derivatized, high surface area, supported nickel catalysts

Abstract

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