C4S82- and C16S184-: Intermediates in the synthesis of poly(carbon sulfide)

Jun Hong Chou, Thomas B. Rauchfuss

Research output: Contribution to journalArticlepeer-review

Abstract

(PPN)2C16S18 was obtained by the addition of PPN+Cl- to a methanolic extract of Na2C4Sx, derived from the reaction of C6S8O2 and NaOMe. Centrosymmetric C16S184- consists of thiophene units unsymmetrically fused to two 1,4-dithiin rings. Solutions of C16S184- convert to C8S82- with heating. When C4Sx (x ∼ 8) is reduced by Na/NH3 followed by extraction and crystallization, one obtains the bicyclic polysulfide C4S82-, crystallized as its PPh4+ salt.

Original languageEnglish (US)
Pages (from-to)1549-1552
Number of pages4
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume52
Issue number12
StatePublished - Dec 1 1997

Keywords

  • Carbon sulfides
  • Inorganic polymer
  • Polysulfide
  • Sulfur
  • Thiophene

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

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