Abstract
A lucky break: A combination of steric pressure and electron asymmetry has provided the first example of a diiron dithiolate that is both rotated and basic. The present work establishes the feasibility of a hydride free rotated structure for the Hred state of the enzyme (see figure).
Original language | English (US) |
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Pages (from-to) | 15476-15479 |
Number of pages | 4 |
Journal | Chemistry - A European Journal |
Volume | 19 |
Issue number | 46 |
DOIs | |
State | Published - Nov 11 2013 |
Keywords
- active site
- co-ligands
- hydrides
- hydrogenase
- iron
ASJC Scopus subject areas
- General Chemistry