Crystallization of 4,4′-biphenyldicarbonitrile with silver(I) salts: A change in topology concomitant with a change in counterion leading to a ninefold diamondoid network

Keith A. Hirsch, D. Venkataraman, Scott R. Wilson, Jeffrey S. Moore, Stephen Lee

Research output: Contribution to journalArticlepeer-review

Abstract

The preparation and X-ray crystal structures of two coordination networks [Ag(BPCN)(CF3SO3)]·C6H6 1 and [Ag(BPCN)2]PF6 2 (BPCN=4,4′-biphenyldicarbonitrile) are described; 1 consists of infinite chains; however, 2 exists as a ninefold interpenetrated diamondoid network.

Original languageEnglish (US)
Pages (from-to)2199-2200
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number21
DOIs
StatePublished - Dec 1 1995

ASJC Scopus subject areas

  • Molecular Medicine

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