Crystal structure of 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene

Yi Ren, Semin Lee, Jeffery A. Bertke, Jeffrey S. Moore

Research output: Contribution to journalArticle

Abstract

The crystal structure of the well-studied 9,10-bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene molecule, C20H12S4, (I), also known as exTTF, is reported. The molecular structure of (I) consists of a dihydroanthracene moiety with two 1,3-dithiol-2-ylidene substituents. This is a saddle-shaped molecule, which interacts with a close neighbor through various π-π and C - H⋯π contacts to form a 'dimer'. These 'dimers' interact through a series of C - H⋯S and C - H⋯π contacts to construct a complex three-dimensional extended structure.

Original languageEnglish (US)
Pages (from-to)1475-1479
Number of pages5
JournalActa Crystallographica Section E: Crystallographic Communications
Volume71
DOIs
StatePublished - 2015

Keywords

  • TTF
  • Wittig-Horner reaction
  • crystal structure
  • exTTF
  • tetrathiafulvalene

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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