TY - JOUR
T1 - Cross-linking dendrimers with allyl ether end-groups using the ring-closing metathesis reaction
AU - Elmer, Stephanie L.
AU - Zimmerman, Steven C.
PY - 2004/10/15
Y1 - 2004/10/15
N2 - A third generation Fréchet-type dendrimer containing 24 allyl ether end-groups was synthesized, cross-linked using the ring-closing metathesis (RCM) reaction, and the core was removed hydrolytically without significant fragmentation. The results are analogous to those previously reported for homoallyl ether dendrimers (Wendland, M. S.; Zimmerman, S. C. J. Am. Chem. Soc. 1999, 121, 1389-1390) suggesting that the less readily available homoallyl ether dendrimers can be replaced by their allyl ethers analogues in a range of applications.
AB - A third generation Fréchet-type dendrimer containing 24 allyl ether end-groups was synthesized, cross-linked using the ring-closing metathesis (RCM) reaction, and the core was removed hydrolytically without significant fragmentation. The results are analogous to those previously reported for homoallyl ether dendrimers (Wendland, M. S.; Zimmerman, S. C. J. Am. Chem. Soc. 1999, 121, 1389-1390) suggesting that the less readily available homoallyl ether dendrimers can be replaced by their allyl ethers analogues in a range of applications.
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U2 - 10.1021/jo049368v
DO - 10.1021/jo049368v
M3 - Article
C2 - 15471495
AN - SCOPUS:5444259360
SN - 0022-3263
VL - 69
SP - 7363
EP - 7366
JO - Journal of Organic Chemistry
JF - Journal of Organic Chemistry
IS - 21
ER -