Coordination of vanadyl acetylacetonate with nitrogen-containing donor bases

A. V. Astashkin, S. A. Dikanov, Yu D. Tsvetkov

Research output: Contribution to journalArticlepeer-review

Abstract

From results obtained in an investigation of modulation effects in the electron spin echo of adducts of VO2+acac2 with nitrogen-containing donor bases, we have been able to determine the constants of HFI of the unpaired electron of the vanadium with the nitrogen nucleus, for a large class of these bases. The values of the HFI constant are in the range 3.6-6 MHz. The sensitivity of modulation effects in ESE to the selection of the base offers a means for determining the relative stability of these adducts.

Original languageEnglish (US)
Pages (from-to)363-368
Number of pages6
JournalJournal of Structural Chemistry
Volume26
Issue number3
DOIs
StatePublished - May 1 1985
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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