Abstract
Various types of transformations require different baselines reflecting specificities of these transitions. The present work deals with the case when a degree of transformation is directly proportional to heat consumed or released. For such case, a baseline is named an integral baseline and is traditionally constructed by unnecessary simplifications. A new method is proposed as an alternative fast and robust computational method for baseline construction utilizing interpolating cubic splines. The method is self-consistent in the sense that it is free of needless assumptions and that it provides linearity between the degree of transformation and heat measured.
Original language | English (US) |
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Pages (from-to) | 595-599 |
Number of pages | 5 |
Journal | Journal of Thermal Analysis and Calorimetry |
Volume | 87 |
Issue number | 2 |
DOIs | |
State | Published - Jan 2007 |
Externally published | Yes |
Keywords
- Baseline
- Cubic splines
- DSC
ASJC Scopus subject areas
- Condensed Matter Physics
- Physical and Theoretical Chemistry