Conjugated polymers for pure UV light emission: Poly(meta-phenylenes)

Dinesh G.Q. Patel, Yu Ya Ohnishi, Yixing Yang, Sang Hyun Eom, Richard T. Farley, Kenneth R. Graham, Jiangeng Xue, So Hirata, Kirk S. Schanze, John R. Reynolds

Research output: Contribution to journalArticle

Abstract

We report the synthesis of a 3-ethylhexyloxy substituted poly(meta-phenylene), EHO-PMP that shows absorption and solid state photoluminescence exclusively in the UV region of the electromagnetic spectrum with an emission maximum of 345 nm. Computational analysis of model oligomers by DFT methods indicates that EHO-PMP is a wide bandgap polymer with the HOMO being localized on a dimeric (biphenyl) unit and with the LUMO being more delocalized. The energy of the LUMO, however, suggests that inefficient electron injection would occur from currently available cathode materials in standard light-emitting device architectures, and this was observed experimentally. The computational results, coupled with experimental observation, lead us to believe that efficient electroluminescence from organic polymer UV emitters requires advances in electron transport layers and cathode materials.

Original languageEnglish (US)
Pages (from-to)557-565
Number of pages9
JournalJournal of Polymer Science, Part B: Polymer Physics
Volume49
Issue number8
DOIs
StatePublished - Apr 15 2011
Externally publishedYes

Keywords

  • UV light emission
  • calculations
  • conjugated polymers
  • light-emitting diodes (LED)
  • polymer

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Materials Chemistry

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  • Cite this

    Patel, D. G. Q., Ohnishi, Y. Y., Yang, Y., Eom, S. H., Farley, R. T., Graham, K. R., Xue, J., Hirata, S., Schanze, K. S., & Reynolds, J. R. (2011). Conjugated polymers for pure UV light emission: Poly(meta-phenylenes). Journal of Polymer Science, Part B: Polymer Physics, 49(8), 557-565. https://doi.org/10.1002/polb.22224