Abstract
Get into shape under redox: Rearrangement of [Ru4S 3(arene)4] accompanies redox processes and occurs in its reduction of H+ to H2 (see scheme; Ru = Ru(cymene)). The [Ru4S3(arene)4]2+ ion is so crowded that arene rotation is hindered, which allows the detection of atropisomers.
Original language | English (US) |
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Pages (from-to) | 6742-6745 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 43 |
Issue number | 48 |
DOIs | |
State | Published - Dec 10 2004 |
Keywords
- Arenes
- Hydrogen
- Rearrangement
- Ruthenium
- Sulfur
ASJC Scopus subject areas
- General Chemistry