Competing H-H, S-S, and M-M bond formation in the "shape- shifting" cluster [Ru4S3(arene)4] 2+

Matthew L. Kuhlman; Thomas Rauchfuss

doi:10.1002/anie.200461264

Competing H-H, S-S, and M-M bond formation in the "shape- shifting" cluster [Ru₄S₃(arene)₄] ²⁺

Matthew L. Kuhlman, Thomas Rauchfuss

Chemistry

Research output: Contribution to journal › Article

Abstract

Get into shape under redox: Rearrangement of [Ru₄S ₃(arene)₄] accompanies redox processes and occurs in its reduction of H⁺ to H₂ (see scheme; Ru = Ru(cymene)). The [Ru₄S₃(arene)₄]²⁺ ion is so crowded that arene rotation is hindered, which allows the detection of atropisomers.

Original language	English (US)
Pages (from-to)	6742-6745
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	43
Issue number	48
DOIs	https://doi.org/10.1002/anie.200461264
State	Published - Dec 10 2004

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Keywords

Arenes
Hydrogen
Rearrangement
Ruthenium
Sulfur

ASJC Scopus subject areas

Chemistry(all)

Cite this

Kuhlman, M. L., & Rauchfuss, T. (2004). Competing H-H, S-S, and M-M bond formation in the "shape- shifting" cluster [Ru₄S₃(arene)₄] ²⁺. Angewandte Chemie - International Edition, 43(48), 6742-6745. https://doi.org/10.1002/anie.200461264

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10.1002/anie.200461264