CO substitution by PPh3in Fe2S2(CO)6proceeds via a novel Fe2S intermediate

Fanjun Zhang; Toby J. Woods; Thomas B. Rauchfuss; Federica Arrigoni; Giuseppe Zampella

doi:10.1039/d1cc00956g

CO substitution by PPh₃in Fe₂S₂(CO)₆proceeds via a novel Fe₂S intermediate

Fanjun Zhang, Toby J. Woods, Thomas B. Rauchfuss, Federica Arrigoni, Giuseppe Zampella

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of Fe2S2(CO)6 and PPh3 affords Fe2S2(CO)4(PPh3)2 by an unprecedented mechanism involving the intermediacy of SPPh3 and Fe2S(CO)6(PPh3)2.

Original language	English (US)
Pages (from-to)	5079-5081
Number of pages	3
Journal	Chemical Communications
Volume	57
Issue number	41
DOIs	https://doi.org/10.1039/d1cc00956g
State	Published - May 21 2021

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Online availability

10.1039/d1cc00956g

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Cite this

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title = "CO substitution by PPh3in Fe2S2(CO)6proceeds via a novel Fe2S intermediate",

abstract = "The reaction of Fe2S2(CO)6 and PPh3 affords Fe2S2(CO)4(PPh3)2 by an unprecedented mechanism involving the intermediacy of SPPh3 and Fe2S(CO)6(PPh3)2.",

author = "Fanjun Zhang and Woods, {Toby J.} and Rauchfuss, {Thomas B.} and Federica Arrigoni and Giuseppe Zampella",

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AU - Zampella, Giuseppe

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