CO substitution by PPh3in Fe2S2(CO)6proceeds via a novel Fe2S intermediate

Fanjun Zhang, Toby J. Woods, Thomas B. Rauchfuss, Federica Arrigoni, Giuseppe Zampella

Research output: Contribution to journalArticlepeer-review


The reaction of Fe2S2(CO)6 and PPh3 affords Fe2S2(CO)4(PPh3)2 by an unprecedented mechanism involving the intermediacy of SPPh3 and Fe2S(CO)6(PPh3)2.

Original languageEnglish (US)
Pages (from-to)5079-5081
Number of pages3
JournalChemical Communications
Issue number41
StatePublished - May 21 2021

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry


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