Chemical Recycling of Polyethylene by Tandem Catalytic Conversion to Propylene

Nicholas M. Wang, Garrett Strong, Vanessa Dasilva, Lijun Gao, Rafael Huacuja, Ivan A. Konstantinov, Mari S. Rosen, Alex J. Nett, Sean Ewart, Roland Geyer, Susannah L. Scott, Damien Guironnet

Research output: Contribution to journalArticlepeer-review


Although polyethylene (PE) and polypropylene (PP) are by far the world's largest volume plastics, only a tiny fraction of these energy-rich polyolefins are currently recycled. Depolymerization of PE to its constituent monomer, ethylene, is highly endothermic and conventionally accessible only through unselective, high-temperature pyrolysis. Here, we provide experimental demonstrations of our recently proposed tandem catalysis strategy, which uses ethylene to convert PE to propylene, the commodity monomer used to make PP. The approach combines rapid olefin metathesis with rate-limiting isomerization. Monounsaturated PE is progressively disassembled at modest temperatures via many consecutive ethenolysis events, resulting selectively in propylene. Fully saturated PE can be converted to unsaturated PE starting with a single transfer dehydrogenation to ethylene, which produces a small amount of ethane (1 equiv per dehydrogenation event). These principles are demonstrated using both homogeneous and heterogeneous catalysts. While selectivity under batch conditions is limited at high conversion by the formation of an equilibrium mixture of olefins, high selectivity to propylene (≥94%) is achieved in a semicontinuous process due to the continuous removal of propylene from the reaction mixture.

Original languageEnglish (US)
Pages (from-to)18526-18531
Number of pages6
JournalJournal of the American Chemical Society
Issue number40
StatePublished - Oct 12 2022

ASJC Scopus subject areas

  • General Chemistry
  • Biochemistry
  • Catalysis
  • Colloid and Surface Chemistry


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