@inbook{3c31422dba184a248f57a45548a9991d,
title = "Chapter 6 Explicitly Correlated Coupled-Cluster Methods",
abstract = "Establishing a hierarchy of rapidly converging, systematic approximations of exact electronic wave functions for general polyatomic molecules is the holy grail of electronic structure theory. Explicitly correlated coupled-cluster (CC-R12) methods, which have recently been developed by us up to a high rank and are reviewed in this chapter, form such a hierarchy; the CC-R12 energies converge most rapidly toward the exact solutions of the Schr{\"o}dinger equations of stable molecules with respect to both the cluster excitation rank and the one-electron basis-set size. The R12 methods in this review are meant to encompass the so-called F12 methods, the term often invoked to distinguish the methods with nonlinear correlation functions (F12) from the linear one (R12).",
keywords = "coupled-cluster methods, explicit-r correlation, higher-order excitations",
author = "Toru Shiozaki and Valeev, {Edward F.} and So Hirata",
note = "Funding Information: We thank Professor Gregory S. Tschumper for the invitation to contribute this review and a critical reading of this manuscript. T. Shiozaki thanks the Japan Society for the Promotion of Science Research Fellowship for Young Scientist and Professor Kimihiko Hirao for his continuous encouragement. E.F. Valeev thanks the Donors of the American Chemical Society Petroleum Research Fund (Grant No. 46811-G6). E.F. Valeev is a Sloan Research Fellow. S. Hirata thanks US Department of Energy (Grant No. DE-FG02-04ER15621) and the Donors of the American Chemical Society Petroleum Research Fund (Grant No. 48440-AC6).",
year = "2009",
doi = "10.1016/S1574-1400(09)00506-4",
language = "English (US)",
isbn = "9780444533593",
series = "Annual Reports in Computational Chemistry",
pages = "131--148",
editor = "Ralph Wheeler",
booktitle = "Annual Reports in Computational Chemistry",
}