catena-poly[{di-μ-nitrato-1:2κ 
                        4
                        O-bis[(tri-phenylphosphine-P)copper(I)]}-μ-4,4′-bipyridyl- N:N′] tetrahydrofuran solvate

Peggy Jean Prest; Jeffrey S. Moore

doi:10.1107/S0108270196006087

catena-poly[{di-μ-nitrato-1:2κ ⁴ O-bis[(tri-phenylphosphine-P)copper(I)]}-μ-4,4′-bipyridyl- N:N′] tetrahydrofuran solvate

Research output: Contribution to journal › Article › peer-review

Abstract

A copper(I) complex with triphenylphosphine and 4,4′-bipyridine results in a one-dimensional polymer, {[Cu₂(NO₃)₂(C₁₈H₁₅P) ₂(C₁₀H₈N₂).2C₄H ₈O}_n. The Cu centers are alternately bridged by nitrate counterions and bipyridine ligands. The four-membered Cu₂O₂ ring lies on an inversion center (1/2-x, 1/2-y, -z) and the bipyridyl ligand lies on another inversion center (1/2-x, 3/2-y, -z). The triphenylphosphine ligand coordinates to copper providing a distorted tetrahedral coordination environment, with bond lengths Cul-P2.168(1), Cu-N 2.013 (3) and Cu-O 2.177 (2) and 2.147 (2) Å. The cavities between the chains contain tetrahydrofuran solvent molecules.

Original language	English (US)
Pages (from-to)	2176-2178
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	9
DOIs	https://doi.org/10.1107/S0108270196006087
State	Published - Sep 15 1996

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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10.1107/S0108270196006087

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Prest, P. J., & Moore, J. S. (1996). catena-poly[{di-μ-nitrato-1:2κ ⁴ O-bis[(tri-phenylphosphine-P)copper(I)]}-μ-4,4′-bipyridyl- N:N′] tetrahydrofuran solvate Acta Crystallographica Section C: Crystal Structure Communications, 52(9), 2176-2178. https://doi.org/10.1107/S0108270196006087

catena-poly[{di-μ-nitrato-1:2κ ⁴ O-bis[(tri-phenylphosphine-P)copper(I)]}-μ-4,4′-bipyridyl- N:N′] tetrahydrofuran solvate . / Prest, Peggy Jean; Moore, Jeffrey S.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 52, No. 9, 15.09.1996, p. 2176-2178.

Research output: Contribution to journal › Article › peer-review

Prest, PJ & Moore, JS 1996, ' catena-poly[{di-μ-nitrato-1:2κ ⁴ O-bis[(tri-phenylphosphine-P)copper(I)]}-μ-4,4′-bipyridyl- N:N′] tetrahydrofuran solvate ', Acta Crystallographica Section C: Crystal Structure Communications, vol. 52, no. 9, pp. 2176-2178. https://doi.org/10.1107/S0108270196006087

Prest PJ, Moore JS. catena-poly[{di-μ-nitrato-1:2κ ⁴ O-bis[(tri-phenylphosphine-P)copper(I)]}-μ-4,4′-bipyridyl- N:N′] tetrahydrofuran solvate Acta Crystallographica Section C: Crystal Structure Communications. 1996 Sep 15;52(9):2176-2178. doi: 10.1107/S0108270196006087

Prest, Peggy Jean ; Moore, Jeffrey S. / catena-poly[{di-μ-nitrato-1:2κ ⁴ O-bis[(tri-phenylphosphine-P)copper(I)]}-μ-4,4′-bipyridyl- N:N′] tetrahydrofuran solvate In: Acta Crystallographica Section C: Crystal Structure Communications. 1996 ; Vol. 52, No. 9. pp. 2176-2178.

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title = " catena-poly[{di-μ-nitrato-1:2κ 4 O-bis[(tri-phenylphosphine-P)copper(I)]}-μ-4,4′-bipyridyl- N:N′] tetrahydrofuran solvate ",

abstract = "A copper(I) complex with triphenylphosphine and 4,4′-bipyridine results in a one-dimensional polymer, {[Cu2(NO3)2(C18H15P) 2(C10H8N2).2C4H 8O}n. The Cu centers are alternately bridged by nitrate counterions and bipyridine ligands. The four-membered Cu2O2 ring lies on an inversion center (1/2-x, 1/2-y, -z) and the bipyridyl ligand lies on another inversion center (1/2-x, 3/2-y, -z). The triphenylphosphine ligand coordinates to copper providing a distorted tetrahedral coordination environment, with bond lengths Cul-P2.168(1), Cu-N 2.013 (3) and Cu-O 2.177 (2) and 2.147 (2) {\AA}. The cavities between the chains contain tetrahydrofuran solvent molecules.",

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N2 - A copper(I) complex with triphenylphosphine and 4,4′-bipyridine results in a one-dimensional polymer, {[Cu2(NO3)2(C18H15P) 2(C10H8N2).2C4H 8O}n. The Cu centers are alternately bridged by nitrate counterions and bipyridine ligands. The four-membered Cu2O2 ring lies on an inversion center (1/2-x, 1/2-y, -z) and the bipyridyl ligand lies on another inversion center (1/2-x, 3/2-y, -z). The triphenylphosphine ligand coordinates to copper providing a distorted tetrahedral coordination environment, with bond lengths Cul-P2.168(1), Cu-N 2.013 (3) and Cu-O 2.177 (2) and 2.147 (2) Å. The cavities between the chains contain tetrahydrofuran solvent molecules.

AB - A copper(I) complex with triphenylphosphine and 4,4′-bipyridine results in a one-dimensional polymer, {[Cu2(NO3)2(C18H15P) 2(C10H8N2).2C4H 8O}n. The Cu centers are alternately bridged by nitrate counterions and bipyridine ligands. The four-membered Cu2O2 ring lies on an inversion center (1/2-x, 1/2-y, -z) and the bipyridyl ligand lies on another inversion center (1/2-x, 3/2-y, -z). The triphenylphosphine ligand coordinates to copper providing a distorted tetrahedral coordination environment, with bond lengths Cul-P2.168(1), Cu-N 2.013 (3) and Cu-O 2.177 (2) and 2.147 (2) Å. The cavities between the chains contain tetrahydrofuran solvent molecules.

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