Carbanion-Accelerated Claisen Rearrangements. 2. Studies on Internal Asymmetric Induction

Scott E. Denmark, Michael A. Harmata

Research output: Contribution to journalArticle

Abstract

The stereochemical couree of Claisen rearrangements of 2 and 3 in the thermal and anionic modes has been studied. The carbanionic processes were shown to be highly stereoselective and dependent upon solvent, counterion, and temperature.

Original languageEnglish (US)
Pages (from-to)3369-3370
Number of pages2
JournalJournal of Organic Chemistry
Volume48
Issue number19
DOIs
StatePublished - Sep 1983

ASJC Scopus subject areas

  • Organic Chemistry

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