C4S 62−: A Bridging Bis(dithiolato) Ligand for the Preparation of Semiconducting Inorganic Polymers

Lisa F. Szczepura; Collin P. Galloway; Yifan Zheng; Pengdi Han; Scott R. Wilson; Thomas B. Rauchfuss; Arnold L. Rheingold

doi:10.1002/anie.199518901

C₄S 62−: A Bridging Bis(dithiolato) Ligand for the Preparation of Semiconducting Inorganic Polymers

Lisa F. Szczepura
, Collin P. Galloway
, Yifan Zheng
, Pengdi Han
, Scott R. Wilson
, Thomas B. Rauchfuss
, Arnold L. Rheingold

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Planar and highly polarizable, the dianionic thiocarbon 1 reacts with metal salts to give inorganic polymers like [Cu₂C₄S₆] and [NiC₄S₆] with semiconductor properties. The Ni coordination polymer forms a one‐dimensional ribbonlike strand of edgesharing square‐planar complexes such as 2. (Figure Presented.)

Original language	English (US)
Pages (from-to)	1890-1892
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	34
Issue number	17
DOIs	https://doi.org/10.1002/anie.199518901
State	Published - Sep 15 1995

Keywords

Polymers
Semiconductors
Sulfur compounds
Thiones

ASJC Scopus subject areas

General Chemistry

Online availability

10.1002/anie.199518901

Library availability

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Cite this

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title = "C4S 62−: A Bridging Bis(dithiolato) Ligand for the Preparation of Semiconducting Inorganic Polymers",

abstract = "Planar and highly polarizable, the dianionic thiocarbon 1 reacts with metal salts to give inorganic polymers like [Cu2C4S6] and [NiC4S6] with semiconductor properties. The Ni coordination polymer forms a one‐dimensional ribbonlike strand of edgesharing square‐planar complexes such as 2. (Figure Presented.)",

keywords = "Polymers, Semiconductors, Sulfur compounds, Thiones",

author = "Szczepura, \{Lisa F.\} and Galloway, \{Collin P.\} and Yifan Zheng and Pengdi Han and Wilson, \{Scott R.\} and Rauchfuss, \{Thomas B.\} and Rheingold, \{Arnold L.\}",

year = "1995",

month = sep,

day = "15",

doi = "10.1002/anie.199518901",

language = "English (US)",

volume = "34",

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journal = "Angewandte Chemie International Edition in English",

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T2 - A Bridging Bis(dithiolato) Ligand for the Preparation of Semiconducting Inorganic Polymers

AU - Szczepura, Lisa F.

AU - Galloway, Collin P.

AU - Zheng, Yifan

AU - Han, Pengdi

AU - Wilson, Scott R.

AU - Rauchfuss, Thomas B.

AU - Rheingold, Arnold L.

PY - 1995/9/15

Y1 - 1995/9/15

N2 - Planar and highly polarizable, the dianionic thiocarbon 1 reacts with metal salts to give inorganic polymers like [Cu2C4S6] and [NiC4S6] with semiconductor properties. The Ni coordination polymer forms a one‐dimensional ribbonlike strand of edgesharing square‐planar complexes such as 2. (Figure Presented.)

AB - Planar and highly polarizable, the dianionic thiocarbon 1 reacts with metal salts to give inorganic polymers like [Cu2C4S6] and [NiC4S6] with semiconductor properties. The Ni coordination polymer forms a one‐dimensional ribbonlike strand of edgesharing square‐planar complexes such as 2. (Figure Presented.)

KW - Polymers

KW - Semiconductors

KW - Sulfur compounds

KW - Thiones

UR - https://www.scopus.com/pages/publications/33748219900

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