C4S 62−: A Bridging Bis(dithiolato) Ligand for the Preparation of Semiconducting Inorganic Polymers

Lisa F. Szczepura; Collin P. Galloway; Yifan Zheng; Pengdi Han; Scott R. Wilson; Thomas B. Rauchfuss; Arnold L. Rheingold

doi:10.1002/anie.199518901

C₄S 62−: A Bridging Bis(dithiolato) Ligand for the Preparation of Semiconducting Inorganic Polymers

Lisa F. Szczepura, Collin P. Galloway, Yifan Zheng, Pengdi Han, Scott R. Wilson, Thomas B. Rauchfuss, Arnold L. Rheingold

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Planar and highly polarizable, the dianionic thiocarbon 1 reacts with metal salts to give inorganic polymers like [Cu₂C₄S₆] and [NiC₄S₆] with semiconductor properties. The Ni coordination polymer forms a one‐dimensional ribbonlike strand of edgesharing square‐planar complexes such as 2. (Figure Presented.)

Original language	English (US)
Pages (from-to)	1890-1892
Number of pages	3
Journal	Angewandte Chemie International Edition in English
Volume	34
Issue number	17
DOIs	https://doi.org/10.1002/anie.199518901
State	Published - Sep 15 1995

Keywords

Polymers
Semiconductors
Sulfur compounds
Thiones

ASJC Scopus subject areas

Chemistry(all)

Online availability

10.1002/anie.199518901

Library availability

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Cite this

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title = "C4S 62−: A Bridging Bis(dithiolato) Ligand for the Preparation of Semiconducting Inorganic Polymers",

abstract = "Planar and highly polarizable, the dianionic thiocarbon 1 reacts with metal salts to give inorganic polymers like [Cu2C4S6] and [NiC4S6] with semiconductor properties. The Ni coordination polymer forms a one‐dimensional ribbonlike strand of edgesharing square‐planar complexes such as 2. (Figure Presented.)",

keywords = "Polymers, Semiconductors, Sulfur compounds, Thiones",

author = "Szczepura, {Lisa F.} and Galloway, {Collin P.} and Yifan Zheng and Pengdi Han and Wilson, {Scott R.} and Rauchfuss, {Thomas B.} and Rheingold, {Arnold L.}",

year = "1995",

month = sep,

day = "15",

doi = "10.1002/anie.199518901",

language = "English (US)",

volume = "34",

pages = "1890--1892",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley & Sons, Ltd.",

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T2 - A Bridging Bis(dithiolato) Ligand for the Preparation of Semiconducting Inorganic Polymers

AU - Szczepura, Lisa F.

AU - Galloway, Collin P.

AU - Zheng, Yifan

AU - Han, Pengdi

AU - Wilson, Scott R.

AU - Rauchfuss, Thomas B.

AU - Rheingold, Arnold L.

PY - 1995/9/15

Y1 - 1995/9/15

N2 - Planar and highly polarizable, the dianionic thiocarbon 1 reacts with metal salts to give inorganic polymers like [Cu2C4S6] and [NiC4S6] with semiconductor properties. The Ni coordination polymer forms a one‐dimensional ribbonlike strand of edgesharing square‐planar complexes such as 2. (Figure Presented.)

AB - Planar and highly polarizable, the dianionic thiocarbon 1 reacts with metal salts to give inorganic polymers like [Cu2C4S6] and [NiC4S6] with semiconductor properties. The Ni coordination polymer forms a one‐dimensional ribbonlike strand of edgesharing square‐planar complexes such as 2. (Figure Presented.)

KW - Polymers

KW - Semiconductors

KW - Sulfur compounds

KW - Thiones

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