C4S 62−: A Bridging Bis(dithiolato) Ligand for the Preparation of Semiconducting Inorganic Polymers

Lisa F. Szczepura, Collin P. Galloway, Yifan Zheng, Pengdi Han, Scott R. Wilson, Thomas B. Rauchfuss, Arnold L. Rheingold

Research output: Contribution to journalArticlepeer-review

Abstract

Planar and highly polarizable, the dianionic thiocarbon 1 reacts with metal salts to give inorganic polymers like [Cu2C4S6] and [NiC4S6] with semiconductor properties. The Ni coordination polymer forms a one‐dimensional ribbonlike strand of edgesharing square‐planar complexes such as 2. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)1890-1892
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume34
Issue number17
DOIs
StatePublished - Sep 15 1995

Keywords

  • Polymers
  • Semiconductors
  • Sulfur compounds
  • Thiones

ASJC Scopus subject areas

  • Chemistry(all)

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