Bis(acetonitrile-κN)(η5-pentamethylcyclopentadienyl) -(pyrimidine-κN)rhodium(III) bis(hexafluoridophosphate)

Julie L. Boyer, Scott R. Wilson, Thomas B. Rauchfuss

Research output: Contribution to journalArticlepeer-review

Abstract

The title compound, [Rh(C10H15)(C4H4N2)(C2H3N)2](PF6)2 or [CpRh(NCMe)2(N2C4H4)](PF6)2, where Cpis penta-methyl-cyclo-penta-dienyl, was obtained from the treatment of an acetonitrile solution of [CpRh(NCMe)3](PF6)2 with an excess of pyrimidine. The RhIII center is coordinated by one Cpring, two acetonitrile ligands and one pyrimidine ligand in a pseudo-octa-hedral geometry. Both PF6 anions are disordered (site occupancies ca 0.4:0.6, and 0.3:0.4:0.3).

Original languageEnglish (US)
Pages (from-to)m2574
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
Issue number10
DOIs
StatePublished - Oct 15 2007

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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