Bis[(1,4,7,10,13,16-hexaoxacyclooctadecane)-potassium] carbonyltricyanorhodate(I) acetonitrile solvate

Curtis M. Whaley; Thomas B. Rauchfuss; Scott R. Wilson

doi:10.1107/S1600536805027297

Bis[(1,4,7,10,13,16-hexaoxacyclooctadecane)-potassium] carbonyltricyanorhodate(I) acetonitrile solvate

Curtis M. Whaley, Thomas B. Rauchfuss, Scott R. Wilson

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the title complex, [K(C₁₂H₂₄)]₂[Rh(CN) ₃(CO)]·C₂H₃N, the Rh atom is coordinated by three cyanide ligands and one carbonyl ligand in a square-planar geometry. The K atom in each cation is coordinated by six O atoms from the crown ether and one N atom from a cyanide ligand.

Original language	English (US)
Pages (from-to)	m1918-m1919
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	61
Issue number	10
DOIs	https://doi.org/10.1107/S1600536805027297
State	Published - Oct 1 2005

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1107/S1600536805027297

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abstract = "In the title complex, [K(C12H24)]2[Rh(CN) 3(CO)]·C2H3N, the Rh atom is coordinated by three cyanide ligands and one carbonyl ligand in a square-planar geometry. The K atom in each cation is coordinated by six O atoms from the crown ether and one N atom from a cyanide ligand.",

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T1 - Bis[(1,4,7,10,13,16-hexaoxacyclooctadecane)-potassium] carbonyltricyanorhodate(I) acetonitrile solvate

AU - Whaley, Curtis M.

AU - Rauchfuss, Thomas B.

AU - Wilson, Scott R.

PY - 2005/10/1

Y1 - 2005/10/1

N2 - In the title complex, [K(C12H24)]2[Rh(CN) 3(CO)]·C2H3N, the Rh atom is coordinated by three cyanide ligands and one carbonyl ligand in a square-planar geometry. The K atom in each cation is coordinated by six O atoms from the crown ether and one N atom from a cyanide ligand.

AB - In the title complex, [K(C12H24)]2[Rh(CN) 3(CO)]·C2H3N, the Rh atom is coordinated by three cyanide ligands and one carbonyl ligand in a square-planar geometry. The K atom in each cation is coordinated by six O atoms from the crown ether and one N atom from a cyanide ligand.

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Bis[(1,4,7,10,13,16-hexaoxacyclooctadecane)-potassium] carbonyltricyanorhodate(I) acetonitrile solvate

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