Beyond Fe-only hydrogenases: N-functionalized 2-aza-1,3-dithiolates Fe2[(SCH2)2NR](CO)x (x = 5, 6)

Joshua D. Lawrence; Hongxiang Li; Thomas B. Rauchfuss

doi:10.1039/b104195a

Beyond Fe-only hydrogenases: N-functionalized 2-aza-1,3-dithiolates Fe₂[(SCH₂)₂NR](CO)_x (x = 5, 6)

Joshua D. Lawrence, Hongxiang Li, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Primary amines undergo chloromethylation with CH₂O/SOCl₂ to give RN(CH₂Cl)₂, which in turn react with Li₂[Fe₂S₂(CO)₆] to give Fe₂[(SCH₂)₂NR](CO)₆; in the case of R = CH₂CH=CH₂ and CH₂CH₂SMe, Me₃NO-induced decarbonylation afforded pentacarbonyl derivatives wherein the pendant functionality is coordinated to Fe.

Original language	English (US)
Pages (from-to)	1482-1483
Number of pages	2
Journal	Chemical Communications
Volume	1
Issue number	16
DOIs	https://doi.org/10.1039/b104195a
State	Published - 2001

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Online availability

10.1039/b104195a

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Cite this

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abstract = "Primary amines undergo chloromethylation with CH2O/SOCl2 to give RN(CH2Cl)2, which in turn react with Li2[Fe2S2(CO)6] to give Fe2[(SCH2)2NR](CO)6; in the case of R = CH2CH=CH2 and CH2CH2SMe, Me3NO-induced decarbonylation afforded pentacarbonyl derivatives wherein the pendant functionality is coordinated to Fe.",

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AB - Primary amines undergo chloromethylation with CH2O/SOCl2 to give RN(CH2Cl)2, which in turn react with Li2[Fe2S2(CO)6] to give Fe2[(SCH2)2NR](CO)6; in the case of R = CH2CH=CH2 and CH2CH2SMe, Me3NO-induced decarbonylation afforded pentacarbonyl derivatives wherein the pendant functionality is coordinated to Fe.

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