Aufbau approach to multimetallic ensembles based on tetrathiooxalate: [Cp*4Rh4(C2S4) 2]2+, [Cp*3Rh2Ru(C2S4)]+, and [Cp*6Rh6(C2S4) 2]4+

Geoffrey A. Holloway; Kevin K. Klausmeyer; Scott R. Wilson; Thomas B. Rauchfuss

doi:10.1021/om000521v

Aufbau approach to multimetallic ensembles based on tetrathiooxalate: [Cp₄Rh₄(C₂S₄) ₂]²⁺, [Cp₃Rh₂Ru(C₂S₄)]⁺, and [Cp*₆Rh₆(C₂S₄) ₂]⁴⁺

Geoffrey A. Holloway, Kevin K. Klausmeyer, Scott R. Wilson, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Experiments aimed at the characterization of new coordination modes for tetrathiooxalate (TTO) are described. Cyclic voltammetric (CV) measurements on Cp*₂Rh₂(C₂S₄) (1) revealed an irreversible oxidation as part of an ECE process that results in the chemically reversible dimerization of 1⁺.

Original language	English (US)
Pages (from-to)	5370-5375
Number of pages	6
Journal	Organometallics
Volume	19
Issue number	25
DOIs	https://doi.org/10.1021/om000521v
State	Published - Dec 11 2000

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Aufbau approach to multimetallic ensembles based on tetrathiooxalate: [Cp*4Rh4(C2S4) 2]2+, [Cp*3Rh2Ru(C2S4)]+, and [Cp*6Rh6(C2S4) 2]4+",

abstract = "Experiments aimed at the characterization of new coordination modes for tetrathiooxalate (TTO) are described. Cyclic voltammetric (CV) measurements on Cp*2Rh2(C2S4) (1) revealed an irreversible oxidation as part of an ECE process that results in the chemically reversible dimerization of 1+.",

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AU - Holloway, Geoffrey A.

AU - Klausmeyer, Kevin K.

AU - Wilson, Scott R.

AU - Rauchfuss, Thomas B.

PY - 2000/12/11

Y1 - 2000/12/11

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AB - Experiments aimed at the characterization of new coordination modes for tetrathiooxalate (TTO) are described. Cyclic voltammetric (CV) measurements on Cp*2Rh2(C2S4) (1) revealed an irreversible oxidation as part of an ECE process that results in the chemically reversible dimerization of 1+.

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