Aufbau approach to multimetallic ensembles based on tetrathiooxalate: [Cp*4Rh4(C2S4) 2]2+, [Cp*3Rh2Ru(C2S4)]+, and [Cp*6Rh6(C2S4) 2]4+

Geoffrey A. Holloway, Kevin K. Klausmeyer, Scott R. Wilson, Thomas B. Rauchfuss

Research output: Contribution to journalArticlepeer-review

Abstract

Experiments aimed at the characterization of new coordination modes for tetrathiooxalate (TTO) are described. Cyclic voltammetric (CV) measurements on Cp*2Rh2(C2S4) (1) revealed an irreversible oxidation as part of an ECE process that results in the chemically reversible dimerization of 1+.

Original languageEnglish (US)
Pages (from-to)5370-5375
Number of pages6
JournalOrganometallics
Volume19
Issue number25
DOIs
StatePublished - Dec 11 2000

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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