Experiments aimed at the characterization of new coordination modes for tetrathiooxalate (TTO) are described. Cyclic voltammetric (CV) measurements on Cp*2Rh2(C2S4) (1) revealed an irreversible oxidation as part of an ECE process that results in the chemically reversible dimerization of 1+.
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry