Asymmetric Carboalkoxyalkylidenation with a Chiral Horner–Wadsworth–Emmons Reagent

Scott E. Denmark; Isaac Rivera

doi:10.1021/jo00102a005

Asymmetric Carboalkoxyalkylidenation with a Chiral Horner–Wadsworth–Emmons Reagent

Scott E. Denmark
, Isaac Rivera

Research output: Contribution to journal › Article › peer-review

Abstract

The asymmetric carboalkoxyalkylidenation of 4-substituted cyclohexanones was effected by the use of chirally modified Horner–Wadsworth–Emmons (HWE) reagents in good yields (78–82%) as well as high levels of enantioselectivity (78–86% ee).

Original language	English (US)
Pages (from-to)	6887-6889
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	59
Issue number	23
DOIs	https://doi.org/10.1021/jo00102a005
State	Published - Nov 1 1994

ASJC Scopus subject areas

Organic Chemistry

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10.1021/jo00102a005

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title = "Asymmetric Carboalkoxyalkylidenation with a Chiral Horner–Wadsworth–Emmons Reagent",

abstract = "The asymmetric carboalkoxyalkylidenation of 4-substituted cyclohexanones was effected by the use of chirally modified Horner–Wadsworth–Emmons (HWE) reagents in good yields (78–82\%) as well as high levels of enantioselectivity (78–86\% ee).",

author = "Denmark, \{Scott E.\} and Isaac Rivera",

year = "1994",

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journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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T1 - Asymmetric Carboalkoxyalkylidenation with a Chiral Horner–Wadsworth–Emmons Reagent

AU - Denmark, Scott E.

AU - Rivera, Isaac

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N2 - The asymmetric carboalkoxyalkylidenation of 4-substituted cyclohexanones was effected by the use of chirally modified Horner–Wadsworth–Emmons (HWE) reagents in good yields (78–82%) as well as high levels of enantioselectivity (78–86% ee).

AB - The asymmetric carboalkoxyalkylidenation of 4-substituted cyclohexanones was effected by the use of chirally modified Horner–Wadsworth–Emmons (HWE) reagents in good yields (78–82%) as well as high levels of enantioselectivity (78–86% ee).

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UR - https://www.scopus.com/pages/publications/0001569397#tab=citedBy

U2 - 10.1021/jo00102a005

DO - 10.1021/jo00102a005

M3 - Article

AN - SCOPUS:0001569397

SN - 0022-3263

VL - 59

SP - 6887

EP - 6889

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 23

ER -

Asymmetric Carboalkoxyalkylidenation with a Chiral Horner–Wadsworth–Emmons Reagent

Abstract

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