Asymmetric Allylation of Aldehydes with Chiral Lewis Bases

Scott E. Denmark, Diane M. Coe, Norman E. Pratt, Brian D. Griedel

Research output: Contribution to journalArticle

Abstract

The asymmetric allylation and crotylation of aromatic aldehydes with allylic trichlorosilanes can be promoted by chiral phosphoramides in high yield and modest enantiomeric excess. The reaction likely proceeds via a hexacoordinate siliconate species.

Original languageEnglish (US)
Pages (from-to)6161-6163
Number of pages3
JournalJournal of Organic Chemistry
Volume59
Issue number21
DOIs
StatePublished - Oct 1 1994

ASJC Scopus subject areas

  • Organic Chemistry

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