Asymmetric [2,3]-Wittig rearrangements with chiral, phosphorus anion-stabilizing groups

Scott E. Denmark; Paula C. Miller

doi:10.1016/00404-0399(50)1391-T

Asymmetric [2,3]-Wittig rearrangements with chiral, phosphorus anion-stabilizing groups

Scott E. Denmark, Paula C. Miller

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The [2,3]-Wittig rearrangement of a chirally-modified phosphorus stabilized anion proceeds readily and with excellent diastereo- and enantioselectivity for allyloxymethyl and (Z)-2-butenyloxymethyl derivatives.

Original language	English (US)
Pages (from-to)	6631-6634
Number of pages	4
Journal	Tetrahedron Letters
Volume	36
Issue number	37
DOIs	https://doi.org/10.1016/00404-0399(50)1391-T
State	Published - Jan 1 1995

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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title = "Asymmetric [2,3]-Wittig rearrangements with chiral, phosphorus anion-stabilizing groups",

abstract = "The [2,3]-Wittig rearrangement of a chirally-modified phosphorus stabilized anion proceeds readily and with excellent diastereo- and enantioselectivity for allyloxymethyl and (Z)-2-butenyloxymethyl derivatives.",

author = "Denmark, {Scott E.} and Miller, {Paula C.}",

year = "1995",

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AU - Miller, Paula C.

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AB - The [2,3]-Wittig rearrangement of a chirally-modified phosphorus stabilized anion proceeds readily and with excellent diastereo- and enantioselectivity for allyloxymethyl and (Z)-2-butenyloxymethyl derivatives.

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