Asymmetric [2,3]-Wittig rearrangements with chiral, phosphorus anion-stabilizing groups

Scott E Denmark, Paula C. Miller

Research output: Contribution to journalArticle

Abstract

The [2,3]-Wittig rearrangement of a chirally-modified phosphorus stabilized anion proceeds readily and with excellent diastereo- and enantioselectivity for allyloxymethyl and (Z)-2-butenyloxymethyl derivatives.

Original languageEnglish (US)
Pages (from-to)6631-6634
Number of pages4
JournalTetrahedron Letters
Volume36
Issue number37
DOIs
StatePublished - Jan 1 1995

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Enantioselectivity
Phosphorus
Anions
Derivatives

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

Cite this

Asymmetric [2,3]-Wittig rearrangements with chiral, phosphorus anion-stabilizing groups. / Denmark, Scott E; Miller, Paula C.

In: Tetrahedron Letters, Vol. 36, No. 37, 01.01.1995, p. 6631-6634.

Research output: Contribution to journalArticle

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