A finite diffusion droplet evaporation model for complex liquid mixture composed of different homogeneous groups is presented in this paper. Separate distribution functions are used to describe the composition of each homogeneous group in the mixture. Only a few parameters are required to describe the mixture. Quasi-steady assumption is applied in the determination of evaporation rates and heat flux to the droplet, and the effects of surface regression, finite diffusion and preferential vaporization of the mixture are included in the liquid phase equations using an effective properties approach. A novel approach was used to reduce the transport equations for the liquid phase to a set of ordinary differential equations. The proposed model is capable in capturing the vaporization characteristics of complex liquid mixtures.