Abstract
The role of multiple reactions in flow-through porous electrodes has been investigated theoretically. The reaction sequences studied include simultaneous deposition of several metals, deposition 01 a metal in the presence of a redox system, and an ECE sequence which is characteristic of many electro-organic synthesis reactions. The model accounts for mass transport, multiple charge transfer reactions, homogeneous chemical reactions, ohmic and geometric parameters. Results are compiled in a series of graphs which elucidate electrode behavior over a wide region of parameter space.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1842-1849 |
| Number of pages | 8 |
| Journal | Journal of the Electrochemical Society |
| Volume | 123 |
| Issue number | 12 |
| DOIs | |
| State | Published - Dec 1976 |
Keywords
- current distribution
- mathematical model
- metal-redox reactions
- multiple-metal deposition
- porous electrode
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Renewable Energy, Sustainability and the Environment
- Surfaces, Coatings and Films
- Electrochemistry
- Materials Chemistry