Alpha Lead Oxide (α-PbO): A New 2D Material with Visible Light Sensitivity

Prashant Kumar, Jing Liu, Pranay Ranjan, Yaowu Hu, Sharma S.R.K.C. Yamijala, Swapan K. Pati, Joseph Irudayaraj, Gary J. Cheng

Research output: Contribution to journalArticle

Abstract

Even though transition metal dichalcogenides (TMDCs) are deemed to be novel photonic and optoelectronic 2D materials, the visible band gap being often limited to monolayer, hampers their potential in niche applications due to fabrication challenges. Uncontrollable defects and degraded functionalities at elevated temperature and under extreme environments further restrict their prospects. To address such limitations, the discovery of a new 2D material, α-PbO is reported. Micromechanical as well as sonochemical exfoliation of 2D atomic sheets of α-PbO are demonstrated and its optical behavior is investigated. Spectroscopic investigations indicate layer dependent band gaps. In particular, even multilayered PbO sheets exhibit visible band gap > 2 eV (direct) which is rare among semiconducting 2D materials. The emission lifetime of multilayer PbO atomic sheets is 7 ns (dim light) as compared to the monolayer which gives 2.5 ns lifetime and an intense light. Density functional theory calculations of layer dependent band structure of α-PbO matches well with experimental results. Experimental findings suggest that PbO atomic sheets exhibit hydrophobic nature, thermal robustness, microwave stability, anti-corrosive behaviour and acid resistance. This new low-cost, abundant and robust 2D material is expected to find many applications in the fields of electronics, optoelectronics, sensors, photocatalysis and energy storage.

Original languageEnglish (US)
Article number1703346
JournalSmall
Volume14
Issue number12
DOIs
StatePublished - Mar 22 2018

Fingerprint

Lead oxide
Photophobia
Photosensitivity
Optics and Photonics
Light
Caustics
Energy gap
Microwaves
Optoelectronic devices
Monolayers
Hot Temperature
Metals
Acid resistance
Costs and Cost Analysis
Temperature
Acids
Photocatalysis
Band structure
Photonics
Energy storage

Keywords

  • band structure calculation
  • lead oxide atomic sheets
  • photoluminescence

ASJC Scopus subject areas

  • Biotechnology
  • Biomaterials
  • Chemistry(all)
  • Materials Science(all)

Cite this

Kumar, P., Liu, J., Ranjan, P., Hu, Y., Yamijala, S. S. R. K. C., Pati, S. K., ... Cheng, G. J. (2018). Alpha Lead Oxide (α-PbO): A New 2D Material with Visible Light Sensitivity. Small, 14(12), [1703346]. https://doi.org/10.1002/smll.201703346

Alpha Lead Oxide (α-PbO) : A New 2D Material with Visible Light Sensitivity. / Kumar, Prashant; Liu, Jing; Ranjan, Pranay; Hu, Yaowu; Yamijala, Sharma S.R.K.C.; Pati, Swapan K.; Irudayaraj, Joseph; Cheng, Gary J.

In: Small, Vol. 14, No. 12, 1703346, 22.03.2018.

Research output: Contribution to journalArticle

Kumar, P, Liu, J, Ranjan, P, Hu, Y, Yamijala, SSRKC, Pati, SK, Irudayaraj, J & Cheng, GJ 2018, 'Alpha Lead Oxide (α-PbO): A New 2D Material with Visible Light Sensitivity', Small, vol. 14, no. 12, 1703346. https://doi.org/10.1002/smll.201703346
Kumar P, Liu J, Ranjan P, Hu Y, Yamijala SSRKC, Pati SK et al. Alpha Lead Oxide (α-PbO): A New 2D Material with Visible Light Sensitivity. Small. 2018 Mar 22;14(12). 1703346. https://doi.org/10.1002/smll.201703346
Kumar, Prashant ; Liu, Jing ; Ranjan, Pranay ; Hu, Yaowu ; Yamijala, Sharma S.R.K.C. ; Pati, Swapan K. ; Irudayaraj, Joseph ; Cheng, Gary J. / Alpha Lead Oxide (α-PbO) : A New 2D Material with Visible Light Sensitivity. In: Small. 2018 ; Vol. 14, No. 12.
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