Alkylation of Chiral, Phosphorus-Stabilized Carbanions: Substituent Effects on the Alkylation Selectivity

Scott E Denmark, Chien Tien Chen

Research output: Contribution to journalArticle

Abstract

The alkylation of a series of enantiomerically pure cis and trans 3-substituted 2-benzyl-6-methyl-1,3,2-oxazaphosphorinane 2-oxides was found to be sensitive to the bulk of the N-substituents.

Original languageEnglish (US)
Pages (from-to)2922-2924
Number of pages3
JournalJournal of Organic Chemistry
Volume59
Issue number11
DOIs
StatePublished - Jun 1 1994

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Alkylation
Phosphorus
Oxides

ASJC Scopus subject areas

  • Organic Chemistry

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Alkylation of Chiral, Phosphorus-Stabilized Carbanions : Substituent Effects on the Alkylation Selectivity. / Denmark, Scott E; Chen, Chien Tien.

In: Journal of Organic Chemistry, Vol. 59, No. 11, 01.06.1994, p. 2922-2924.

Research output: Contribution to journalArticle

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abstract = "The alkylation of a series of enantiomerically pure cis and trans 3-substituted 2-benzyl-6-methyl-1,3,2-oxazaphosphorinane 2-oxides was found to be sensitive to the bulk of the N-substituents.",
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