Alkylation of Chiral, Phosphorus-Stabilized Carbanions: Substituent Effects on the Alkylation Selectivity

Scott E. Denmark; Chien Tien Chen

doi:10.1021/jo00090a004

Alkylation of Chiral, Phosphorus-Stabilized Carbanions: Substituent Effects on the Alkylation Selectivity

Scott E. Denmark, Chien Tien Chen

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The alkylation of a series of enantiomerically pure cis and trans 3-substituted 2-benzyl-6-methyl-1,3,2-oxazaphosphorinane 2-oxides was found to be sensitive to the bulk of the N-substituents.

Original language	English (US)
Pages (from-to)	2922-2924
Number of pages	3
Journal	Journal of Organic Chemistry
Volume	59
Issue number	11
DOIs	https://doi.org/10.1021/jo00090a004
State	Published - Jun 1 1994

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Organic Chemistry

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10.1021/jo00090a004

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title = "Alkylation of Chiral, Phosphorus-Stabilized Carbanions: Substituent Effects on the Alkylation Selectivity",

abstract = "The alkylation of a series of enantiomerically pure cis and trans 3-substituted 2-benzyl-6-methyl-1,3,2-oxazaphosphorinane 2-oxides was found to be sensitive to the bulk of the N-substituents.",

author = "Denmark, {Scott E.} and Chen, {Chien Tien}",

year = "1994",

month = jun,

day = "1",

doi = "10.1021/jo00090a004",

language = "English (US)",

volume = "59",

pages = "2922--2924",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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T2 - Substituent Effects on the Alkylation Selectivity

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AU - Chen, Chien Tien

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N2 - The alkylation of a series of enantiomerically pure cis and trans 3-substituted 2-benzyl-6-methyl-1,3,2-oxazaphosphorinane 2-oxides was found to be sensitive to the bulk of the N-substituents.

AB - The alkylation of a series of enantiomerically pure cis and trans 3-substituted 2-benzyl-6-methyl-1,3,2-oxazaphosphorinane 2-oxides was found to be sensitive to the bulk of the N-substituents.

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JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

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Alkylation of Chiral, Phosphorus-Stabilized Carbanions: Substituent Effects on the Alkylation Selectivity

Abstract

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