Aikylldenebis(perthiolates): A New Class of OrganosuHur Ligands Prepared from (RC5H4)2TIS5

Dean M. Giolando; Thomas B. Rauchfuss

doi:10.1021/om00081a026

Aikylldenebis(perthiolates): A New Class of OrganosuHur Ligands Prepared from (RC₅H₄)₂TIS₅

Dean M. Giolando
, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the presence of (NH₄J₂S, (RC₅H₄)₂TiS₅ (R = H, Me, i-Pr) reacts with aliphatic ketones and CH₂Br₂ to give 1,4-(RC₅H₄)₂TiS₄CR₂ (R₂ = Me₂; Me, Et; c-C₆H₁₀; H₂) and 1,3-(RC₅H₄)₂TiS₄CH₂. The new compounds were purified chromatographically and were characterized spectroscopically including DNMR spectroscopy. Single-crystal X-ray crystallography confirmed the structure of (i-PrC₅H₄)₂TiS₄CH₂.

Original language	English (US)
Pages (from-to)	487-489
Number of pages	3
Journal	Organometallics
Volume	3
Issue number	3
DOIs	https://doi.org/10.1021/om00081a026
State	Published - Jan 1984

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00081a026

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title = "Aikylldenebis(perthiolates): A New Class of OrganosuHur Ligands Prepared from (RC5H4)2TIS5",

abstract = "In the presence of (NH4J2S, (RC5H4)2TiS5 (R = H, Me, i-Pr) reacts with aliphatic ketones and CH2Br2 to give 1,4-(RC5H4)2TiS4CR2 (R2 = Me2; Me, Et; c-C6H10; H2) and 1,3-(RC5H4)2TiS4CH2. The new compounds were purified chromatographically and were characterized spectroscopically including DNMR spectroscopy. Single-crystal X-ray crystallography confirmed the structure of (i-PrC5H4)2TiS4CH2.",

author = "Giolando, \{Dean M.\} and Rauchfuss, \{Thomas B.\}",

year = "1984",

month = jan,

doi = "10.1021/om00081a026",

language = "English (US)",

volume = "3",

pages = "487--489",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "3",

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T1 - Aikylldenebis(perthiolates)

T2 - A New Class of OrganosuHur Ligands Prepared from (RC5H4)2TIS5

AU - Giolando, Dean M.

AU - Rauchfuss, Thomas B.

PY - 1984/1

Y1 - 1984/1

N2 - In the presence of (NH4J2S, (RC5H4)2TiS5 (R = H, Me, i-Pr) reacts with aliphatic ketones and CH2Br2 to give 1,4-(RC5H4)2TiS4CR2 (R2 = Me2; Me, Et; c-C6H10; H2) and 1,3-(RC5H4)2TiS4CH2. The new compounds were purified chromatographically and were characterized spectroscopically including DNMR spectroscopy. Single-crystal X-ray crystallography confirmed the structure of (i-PrC5H4)2TiS4CH2.

AB - In the presence of (NH4J2S, (RC5H4)2TiS5 (R = H, Me, i-Pr) reacts with aliphatic ketones and CH2Br2 to give 1,4-(RC5H4)2TiS4CR2 (R2 = Me2; Me, Et; c-C6H10; H2) and 1,3-(RC5H4)2TiS4CH2. The new compounds were purified chromatographically and were characterized spectroscopically including DNMR spectroscopy. Single-crystal X-ray crystallography confirmed the structure of (i-PrC5H4)2TiS4CH2.

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