Aikylldenebis(perthiolates): A New Class of OrganosuHur Ligands Prepared from (RC5H4)2TIS5

Dean M. Giolando, Thomas B. Rauchfuss

Research output: Contribution to journalArticlepeer-review


In the presence of (NH4J2S, (RC5H4)2TiS5 (R = H, Me, i-Pr) reacts with aliphatic ketones and CH2Br2 to give 1,4-(RC5H4)2TiS4CR2 (R2 = Me2; Me, Et; c-C6H10; H2) and 1,3-(RC5H4)2TiS4CH2. The new compounds were purified chromatographically and were characterized spectroscopically including DNMR spectroscopy. Single-crystal X-ray crystallography confirmed the structure of (i-PrC5H4)2TiS4CH2.

Original languageEnglish (US)
Pages (from-to)487-489
Number of pages3
Issue number3
StatePublished - Jan 1984

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry


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