Aikylldenebis(perthiolates): A New Class of OrganosuHur Ligands Prepared from (RC5H4)2TIS5

Dean M. Giolando; Thomas B. Rauchfuss

doi:10.1021/om00081a026

Aikylldenebis(perthiolates): A New Class of OrganosuHur Ligands Prepared from (RC₅H₄)₂TIS₅

Dean M. Giolando, Thomas B. Rauchfuss

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In the presence of (NH₄J₂S, (RC₅H₄)₂TiS₅ (R = H, Me, i-Pr) reacts with aliphatic ketones and CH₂Br₂ to give 1,4-(RC₅H₄)₂TiS₄CR₂ (R₂ = Me₂; Me, Et; c-C₆H₁₀; H₂) and 1,3-(RC₅H₄)₂TiS₄CH₂. The new compounds were purified chromatographically and were characterized spectroscopically including DNMR spectroscopy. Single-crystal X-ray crystallography confirmed the structure of (i-PrC₅H₄)₂TiS₄CH₂.

Original language	English (US)
Pages (from-to)	487-489
Number of pages	3
Journal	Organometallics
Volume	3
Issue number	3
DOIs	https://doi.org/10.1021/om00081a026
State	Published - Jan 1984

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Online availability

10.1021/om00081a026

Library availability

Discover UIUC Full Text

Cite this

@article{577a29956d76420da5a451cfccce7a7c,

title = "Aikylldenebis(perthiolates): A New Class of OrganosuHur Ligands Prepared from (RC5H4)2TIS5",

abstract = "In the presence of (NH4J2S, (RC5H4)2TiS5 (R = H, Me, i-Pr) reacts with aliphatic ketones and CH2Br2 to give 1,4-(RC5H4)2TiS4CR2 (R2 = Me2; Me, Et; c-C6H10; H2) and 1,3-(RC5H4)2TiS4CH2. The new compounds were purified chromatographically and were characterized spectroscopically including DNMR spectroscopy. Single-crystal X-ray crystallography confirmed the structure of (i-PrC5H4)2TiS4CH2.",

author = "Giolando, {Dean M.} and Rauchfuss, {Thomas B.}",

year = "1984",

month = jan,

doi = "10.1021/om00081a026",

language = "English (US)",

volume = "3",

pages = "487--489",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - Aikylldenebis(perthiolates)

T2 - A New Class of OrganosuHur Ligands Prepared from (RC5H4)2TIS5

AU - Giolando, Dean M.

AU - Rauchfuss, Thomas B.

PY - 1984/1

Y1 - 1984/1

N2 - In the presence of (NH4J2S, (RC5H4)2TiS5 (R = H, Me, i-Pr) reacts with aliphatic ketones and CH2Br2 to give 1,4-(RC5H4)2TiS4CR2 (R2 = Me2; Me, Et; c-C6H10; H2) and 1,3-(RC5H4)2TiS4CH2. The new compounds were purified chromatographically and were characterized spectroscopically including DNMR spectroscopy. Single-crystal X-ray crystallography confirmed the structure of (i-PrC5H4)2TiS4CH2.

AB - In the presence of (NH4J2S, (RC5H4)2TiS5 (R = H, Me, i-Pr) reacts with aliphatic ketones and CH2Br2 to give 1,4-(RC5H4)2TiS4CR2 (R2 = Me2; Me, Et; c-C6H10; H2) and 1,3-(RC5H4)2TiS4CH2. The new compounds were purified chromatographically and were characterized spectroscopically including DNMR spectroscopy. Single-crystal X-ray crystallography confirmed the structure of (i-PrC5H4)2TiS4CH2.

UR - http://www.scopus.com/inward/record.url?scp=0001141510&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001141510&partnerID=8YFLogxK

U2 - 10.1021/om00081a026

DO - 10.1021/om00081a026

M3 - Article

AN - SCOPUS:0001141510

SN - 0276-7333

VL - 3

SP - 487

EP - 489

JO - Organometallics

JF - Organometallics

IS - 3

ER -