Adsorption of cobalt phthalocyanine on Si(1 0 0)2 × 1 and Si(1 0 0)2 × 1:H surfaces studied by scanning tunneling microscopy and spectroscopy

Lequn Liu, Jixin Yu, Neil O.L. Viernes, Jeffrey S. Moore, Joseph W. Lyding

Research output: Contribution to journalArticle

Abstract

Ultra-high vacuum, scanning tunneling microscopy (STM) and spectroscopy (STS) are used to study isolated cobalt phthalocyanine (CoPc) molecules adsorbed on both the Si(1 0 0)2 × 1 surface and single dangling bonds of the Si(1 0 0)2 × 1:H surface. Three major adsorption configurations are observed on the Si(1 0 0)2 × 1 surface consisting of a fourfold molecular image characteristic of CoPc but possessing different central structural features. However, images obtained on the Si(1 0 0)2 × 1:H surface correspond to molecular rotation of CoPc parallel to the surface. STM, STS, current image tunneling spectroscopy and molecular modeling are used to investigate the different interactions between CoPc and these two Si substrates, as well as their effects upon the electronic charge distribution and the geometric configurations of the adsorbed CoPc molecules.

Original languageEnglish (US)
Pages (from-to)118-126
Number of pages9
JournalSurface Science
Volume516
Issue number1-2
DOIs
StatePublished - Sep 10 2002

Fingerprint

Scanning tunneling microscopy
scanning tunneling microscopy
Cobalt
cobalt
Spectroscopy
Adsorption
adsorption
spectroscopy
molecular rotation
Molecules
Dangling bonds
Molecular modeling
Charge distribution
Ultrahigh vacuum
configurations
charge distribution
ultrahigh vacuum
molecules
cobalt phthalocyanine
Substrates

Keywords

  • Adsorption kinetics
  • Cobalt
  • Computer simulations
  • Hydrogen atom
  • Scanning tunneling microscopy
  • Silicon
  • Surface electronic phenomena (work function, surface potential, surface states, etc.)

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Condensed Matter Physics
  • Surfaces and Interfaces

Cite this

Adsorption of cobalt phthalocyanine on Si(1 0 0)2 × 1 and Si(1 0 0)2 × 1:H surfaces studied by scanning tunneling microscopy and spectroscopy. / Liu, Lequn; Yu, Jixin; Viernes, Neil O.L.; Moore, Jeffrey S.; Lyding, Joseph W.

In: Surface Science, Vol. 516, No. 1-2, 10.09.2002, p. 118-126.

Research output: Contribution to journalArticle

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abstract = "Ultra-high vacuum, scanning tunneling microscopy (STM) and spectroscopy (STS) are used to study isolated cobalt phthalocyanine (CoPc) molecules adsorbed on both the Si(1 0 0)2 × 1 surface and single dangling bonds of the Si(1 0 0)2 × 1:H surface. Three major adsorption configurations are observed on the Si(1 0 0)2 × 1 surface consisting of a fourfold molecular image characteristic of CoPc but possessing different central structural features. However, images obtained on the Si(1 0 0)2 × 1:H surface correspond to molecular rotation of CoPc parallel to the surface. STM, STS, current image tunneling spectroscopy and molecular modeling are used to investigate the different interactions between CoPc and these two Si substrates, as well as their effects upon the electronic charge distribution and the geometric configurations of the adsorbed CoPc molecules.",
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AU - Lyding, Joseph W.

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