Abstract
In the presence of oxidants such as amine oxides, nitriles add to [ReS4]- ions to give bicyclic adducts (structure of the CF3CN adduct on the right). This reaction provides a new model for the activation of unsaturated nitrogen compounds by metal sulfides, which are known to be good catalysts for the hydrogenation of such substrates.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2083-2085 |
| Number of pages | 3 |
| Journal | Angewandte Chemie (International Edition in English) |
| Volume | 36 |
| Issue number | 19 |
| DOIs | |
| State | Published - 1997 |
Keywords
- Nitrogen fixation
- Oxidoreductases
- Redox chemistry
- Rhenium
- Sulfur
ASJC Scopus subject areas
- General Chemistry
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