Absorption spectrum of flexible conjugated polymers: the weak-disorder limit

Z. G. Soos, K. S. Schweizer

Research output: Contribution to journalArticlepeer-review

Abstract

Purely conformational contributions to dipole transition moments lead to a general new expression for the absorption spectrum of flexible conjugated polymers with persistence length ξc and alternation δ. Blue-shifts are found at rod-to-coil transitions without invoking rotational defects that break the conjugation. Conformational coupling in the weak-disorder limit increases the effective alternation.

Original languageEnglish (US)
Pages (from-to)196-200
Number of pages5
JournalChemical Physics Letters
Volume139
Issue number2
DOIs
StatePublished - Aug 21 1987
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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