A vinylsilane route to trans-7a-methylhydrind-4-en-1,6-dione

Scott E. Denmark; Juris P. Germanas

doi:10.1016/S0040-4039(01)80120-9

A vinylsilane route to trans-7a-methylhydrind-4-en-1,6-dione

Scott E. Denmark, Juris P. Germanas

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

A stereoselective synthesis of the title compound is described. The overall yield is 34% starting with 2-methyl-2-cyclopentenone. The trans ring-fusion stereochemistry is established by a conjugate addition/trapping sequence.

Original language	English (US)
Pages (from-to)	1231-1234
Number of pages	4
Journal	Tetrahedron Letters
Volume	25
Issue number	12
DOIs	https://doi.org/10.1016/S0040-4039(01)80120-9
State	Published - 1984

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4039(01)80120-9

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title = "A vinylsilane route to trans-7a-methylhydrind-4-en-1,6-dione",

abstract = "A stereoselective synthesis of the title compound is described. The overall yield is 34% starting with 2-methyl-2-cyclopentenone. The trans ring-fusion stereochemistry is established by a conjugate addition/trapping sequence.",

author = "Denmark, {Scott E.} and Germanas, {Juris P.}",

year = "1984",

doi = "10.1016/S0040-4039(01)80120-9",

language = "English (US)",

volume = "25",

pages = "1231--1234",

journal = "Tetrahedron Letters",

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T1 - A vinylsilane route to trans-7a-methylhydrind-4-en-1,6-dione

AU - Denmark, Scott E.

AU - Germanas, Juris P.

PY - 1984

Y1 - 1984

N2 - A stereoselective synthesis of the title compound is described. The overall yield is 34% starting with 2-methyl-2-cyclopentenone. The trans ring-fusion stereochemistry is established by a conjugate addition/trapping sequence.

AB - A stereoselective synthesis of the title compound is described. The overall yield is 34% starting with 2-methyl-2-cyclopentenone. The trans ring-fusion stereochemistry is established by a conjugate addition/trapping sequence.

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U2 - 10.1016/S0040-4039(01)80120-9

DO - 10.1016/S0040-4039(01)80120-9

M3 - Article

AN - SCOPUS:0010316187

SN - 0040-4039

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EP - 1234

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 12

ER -

A vinylsilane route to trans-7a-methylhydrind-4-en-1,6-dione

Abstract

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