A tris(μ-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue

Liviu M. Mirica, T. Daniel P. Stack

Research output: Contribution to journalArticle

Abstract

The reaction of a copper(I) complex with a sterically demanding secondary diamine ligand and O2 yields a tris(μ-hydroxy)tricopper-(II) complex. This complex is a structural model of the proposed native intermediate in multicopper oxidases, with interesting structural, magnetic, and solution properties.

Original languageEnglish (US)
Pages (from-to)2131-2133
Number of pages3
JournalInorganic Chemistry
Volume44
Issue number7
DOIs
StatePublished - Apr 7 2005
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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