A tris(μ-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue

Liviu M. Mirica; T. Daniel P. Stack

doi:10.1021/ic048182b

A tris(μ-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue

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Abstract

The reaction of a copper(I) complex with a sterically demanding secondary diamine ligand and O₂ yields a tris(μ-hydroxy)tricopper-(II) complex. This complex is a structural model of the proposed native intermediate in multicopper oxidases, with interesting structural, magnetic, and solution properties.

Original language	English (US)
Pages (from-to)	2131-2133
Number of pages	3
Journal	Inorganic Chemistry
Volume	44
Issue number	7
DOIs	https://doi.org/10.1021/ic048182b
State	Published - Apr 7 2005
Externally published	Yes

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/ic048182b

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A tris(μ-hydroxy)tricopper(II) complex as a model of the native intermediate in laccase and its relationship to a binuclear analogue

Abstract

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