A single-sweep, nanosecond time resolution laser temperature-jump apparatus

R. M. Ballew, J. Sabelko, C. Reiner, M. Gruebele

Research output: Contribution to journalArticlepeer-review

Abstract

We describe a fast temperature-jump (T-jump) apparatus capable of acquiring kinetic relaxation transients via real-time fluorescence detection over a time interval from nanoseconds to milliseconds in a single sweep. The method is suitable for aqueous solutions, relying upon the direct absorption of laser light by the bulk water. This obviates the need for additives (serving as optical or conductive heaters) that may interact with the sample under investigation. The longitudinal temperature profile is made uniform by counterpropagating heating pulses. Dead time is limited to one period of the probe laser (16 ns). The apparatus response is tested with aqueous tryptophan and the diffusion-controlled dimerization of proflavine.

Original languageEnglish (US)
Pages (from-to)3694-3699
Number of pages6
JournalReview of Scientific Instruments
Volume67
Issue number10
DOIs
StatePublished - Oct 1996
Externally publishedYes

ASJC Scopus subject areas

  • Instrumentation

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