TY - JOUR
T1 - A silver(I) complex of 4,4′-dicyanodiphenylacetylene with a difluorophosphate (PO2F2-) counterion
AU - Hirsch, Keith A.
AU - Wilson, Scott R.
AU - Moore, Jeffrey S.
PY - 1996/10/15
Y1 - 1996/10/15
N2 - Crystallization of 1,2-ethynediylbis(4-benzonitrile) with silver(I) hexafluorophosphate results in hydrolysis of the counterion to the difluorophosphate species. The resulting complex, poly[disilver(I)-bis(μ 3-difluorophosphato-O:O:O′)-μ-[1,2-ethynediylbis(4- benzonitrile)-N:N]], [Ag2(F2O2P)2(C16H8N 2)]∞, consists of infinite chains of ligands coordinated to silver(I) which are linked through counterion O atoms to form undulating sheets.
AB - Crystallization of 1,2-ethynediylbis(4-benzonitrile) with silver(I) hexafluorophosphate results in hydrolysis of the counterion to the difluorophosphate species. The resulting complex, poly[disilver(I)-bis(μ 3-difluorophosphato-O:O:O′)-μ-[1,2-ethynediylbis(4- benzonitrile)-N:N]], [Ag2(F2O2P)2(C16H8N 2)]∞, consists of infinite chains of ligands coordinated to silver(I) which are linked through counterion O atoms to form undulating sheets.
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U2 - 10.1107/S0108270196005173
DO - 10.1107/S0108270196005173
M3 - Article
AN - SCOPUS:0030259891
SN - 0108-2701
VL - 52
SP - 2419
EP - 2422
JO - Acta Crystallographica, Section C: Crystal Structure Communications
JF - Acta Crystallographica, Section C: Crystal Structure Communications
IS - 10
ER -