A silver(I) complex of 4,4′-dicyanodiphenylacetylene with a difluorophosphate (PO2F2-) counterion

Keith A. Hirsch; Scott R. Wilson; Jeffrey S. Moore

doi:10.1107/S0108270196005173

A silver(I) complex of 4,4′-dicyanodiphenylacetylene with a difluorophosphate (PO₂F₂^-) counterion

Keith A. Hirsch, Scott R. Wilson, Jeffrey S. Moore

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Abstract

Crystallization of 1,2-ethynediylbis(4-benzonitrile) with silver(I) hexafluorophosphate results in hydrolysis of the counterion to the difluorophosphate species. The resulting complex, poly[disilver(I)-bis(μ ₃-difluorophosphato-O:O:O′)-μ-[1,2-ethynediylbis(4- benzonitrile)-N:N]], [Ag2(F₂O₂P)₂(C₁₆H₈N ₂)]∞, consists of infinite chains of ligands coordinated to silver(I) which are linked through counterion O atoms to form undulating sheets.

Original language	English (US)
Pages (from-to)	2419-2422
Number of pages	4
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	10
DOIs	https://doi.org/10.1107/S0108270196005173
State	Published - Oct 15 1996

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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10.1107/S0108270196005173

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title = "A silver(I) complex of 4,4′-dicyanodiphenylacetylene with a difluorophosphate (PO2F2-) counterion",

abstract = "Crystallization of 1,2-ethynediylbis(4-benzonitrile) with silver(I) hexafluorophosphate results in hydrolysis of the counterion to the difluorophosphate species. The resulting complex, poly[disilver(I)-bis(μ 3-difluorophosphato-O:O:O′)-μ-[1,2-ethynediylbis(4- benzonitrile)-N:N]], [Ag2(F2O2P)2(C16H8N 2)]∞, consists of infinite chains of ligands coordinated to silver(I) which are linked through counterion O atoms to form undulating sheets.",

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AU - Wilson, Scott R.

AU - Moore, Jeffrey S.

PY - 1996/10/15

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N2 - Crystallization of 1,2-ethynediylbis(4-benzonitrile) with silver(I) hexafluorophosphate results in hydrolysis of the counterion to the difluorophosphate species. The resulting complex, poly[disilver(I)-bis(μ 3-difluorophosphato-O:O:O′)-μ-[1,2-ethynediylbis(4- benzonitrile)-N:N]], [Ag2(F2O2P)2(C16H8N 2)]∞, consists of infinite chains of ligands coordinated to silver(I) which are linked through counterion O atoms to form undulating sheets.

AB - Crystallization of 1,2-ethynediylbis(4-benzonitrile) with silver(I) hexafluorophosphate results in hydrolysis of the counterion to the difluorophosphate species. The resulting complex, poly[disilver(I)-bis(μ 3-difluorophosphato-O:O:O′)-μ-[1,2-ethynediylbis(4- benzonitrile)-N:N]], [Ag2(F2O2P)2(C16H8N 2)]∞, consists of infinite chains of ligands coordinated to silver(I) which are linked through counterion O atoms to form undulating sheets.

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