A silver(I) complex of 4,4′-dicyanodiphenylacetylene with a difluorophosphate (PO2F2-) counterion

Keith A. Hirsch, Scott R. Wilson, Jeffrey S. Moore

Research output: Contribution to journalArticlepeer-review

Abstract

Crystallization of 1,2-ethynediylbis(4-benzonitrile) with silver(I) hexafluorophosphate results in hydrolysis of the counterion to the difluorophosphate species. The resulting complex, poly[disilver(I)-bis(μ 3-difluorophosphato-O:O:O′)-μ-[1,2-ethynediylbis(4- benzonitrile)-N:N]], [Ag2(F2O2P)2(C16H8N 2)]∞, consists of infinite chains of ligands coordinated to silver(I) which are linked through counterion O atoms to form undulating sheets.

Original languageEnglish (US)
Pages (from-to)2419-2422
Number of pages4
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume52
Issue number10
DOIs
StatePublished - Oct 15 1996

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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