Abstract
A convenient synthesis of trisamido molybdenum(VI) alkylidyne complexes has been developed, in which the key step is the addition of a geminal dichloride to a trisamido molybdenum(III) complex in the presence of magnesium to continuously recycle unwanted side product 4, selectively generating the desired alkylidyne complexes in high yield.
Original language | English (US) |
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Pages (from-to) | 832-833 |
Number of pages | 2 |
Journal | Chemical Communications |
Volume | 3 |
Issue number | 7 |
DOIs | |
State | Published - 2003 |
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- General Chemistry
- Ceramics and Composites
- Metals and Alloys
- Materials Chemistry
- Surfaces, Coatings and Films
- Catalysis