A photoactive semisynthetic metalloenzyme exhibits complete selectivity for CO₂ reduction in water

Keyphrases

• Ruthenium 100%
• Metalloenzymes 100%
• CO2 Reduction Reaction (CO2RR) 100%
• Photoactive 100%
• Ni(II) 100%
• Semi-synthetic 100%
• Cyclam 100%
• Intramolecular Electron Transfer 50%
• Azurin 50%
• Chromophore 50%
• Protein Scaffold 50%
• Electrostatic Effect 50%
• Stern-Volmer Analysis 50%
• Photophysics 50%
• Light-driven 50%
• Photo-generated 50%
• Sacrificial Electron Donor 50%
• Molecular Catalyst 50%
• Artificial Metalloenzymes 50%
• Excited State Electron Transfer 50%
• Semisynthetic Enzymes 50%

Chemistry

• Electron Transport 100%
• Electron Transfer 100%
• Ruthenium 100%
• Metalloenzyme 100%
• Carbon Dioxide Reduction 100%
• Hydrogen 50%
• Chromophore 50%
• Excited State 50%
• Ascorbate 50%
• Photophysics 50%
• Electron Donor 50%